Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4

Base Information

• Chemical Name: Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4
• CAS No.: 54353-74-1
• Molecular Formula: CO*C₂₄H₂₀B*C₄₂H₄₂NP₃*Co
• Molecular Weight: 1059.96
• Mol file: 54353-74-1.mol

Synonyms:

Chemical Property of Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4

There total 4 articles about Co⁽¹⁺⁾*(N(CH₂CH₂P(C₆H₅)2)3)*(CO)*B(C₆H₅)4^(1-)=[Co(N(CH₂CH₂P(C₆H₅)2)3)(CO)]B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

bis[[tris(2-diphenylphosphinoethyl)amine-NP'P''P''']cobaltio]dimercury(Hg-Hg)*tetrahydrofuran + sodium tetraphenyl borate (143-66-8) → Co(1+)*(N(CH2CH2P(C6H5)2)3)*(CO)*B(C6H5)4(1-)=[Co(N(CH2CH2P(C6H5)2)3)(CO)]B(C6H5)4 (54353-74-1,97135-37-0)

Guidance literature:

With CO; In tetrahydrofuran; dibutyl ether; byproducts: Hg; CO bubbled through soln. of Co-complex in THF for 30 min at 25°C, Hg sepd. by decantation, di-n-butyl ether added, soln. concd. by bubbling N2, added soln. of NaBPh4 in THF; ppt. sepd.;

DOI:10.1039/DT9830000349

Reference yield: 60.0%

(tris[2-(diphenylphsophino)ethyl]amino)CoH (53687-39-1) + sodium tetraphenyl borate (143-66-8) → [(tris(2-(diphenylphosphino)ethyl)amine)Co(CO)]BPh4 (97135-37-0,54353-74-1)

Guidance literature:

With carbon oxide sulfide; In tetrahydrofuran; carbonyl sulfide was bubbled for 15 min through the suspn. of complex, then NaBPh4 in n-butanol was added, N2 atm.; filtration, washing with ethanol and petroleum ether;

Reference yield: 50.0%

(tris(2-(diphenylphosphino)ethyl)amine)CoH (53687-39-1,97135-32-5) + sodium tetraphenyl borate (143-66-8) → [(OP(C6H5)2CH2CH2N(CH2CH2P(C6H5)2)2)Co](2+)*2B(C6H5)4(1-)=[(OP(C6H5)2CH2CH2N(CH2CH2P(C6H5)2)2)Co](B(C6H5)4)2 + [(tris(2-(diphenylphosphino)ethyl)amine)Co(CO)]BPh4 (97135-37-0,54353-74-1)

Guidance literature:

With CO₂; dicyclohexano-18-crown-6; In tetrahydrofuran; addn. of THF soln. of NaBPh4 and dicyclohexano-18-crown-6 to soln. of Co complex, bubbling CO2 for a few minutes;

DOI:10.1021/ja00321a036

upstream raw materials:

(tris(2-(diphenylphosphino)ethyl)amine)CoH

sodium tetraphenyl borate

(tris[2-(diphenylphsophino)ethyl]amino)CoH

phenyl isocyanate