15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (E)-6,6-bis-benzenesulfonyl-hex-4-enyl ester

Base Information

• Chemical Name: 15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (E)-6,6-bis-benzenesulfonyl-hex-4-enyl ester
• CAS No.: 110815-15-1
• Molecular Formula: C₅₃H₇₀O₈S₂Si
• Molecular Weight: 927.351
• Mol file: 110815-15-1.mol

Synonyms:

Chemical Property of 15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (E)-6,6-bis-benzenesulfonyl-hex-4-enyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (E)-6,6-bis-benzenesulfonyl-hex-4-enyl ester

There total 1 articles about 15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (E)-6,6-bis-benzenesulfonyl-hex-4-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-6,6-Bis-benzenesulfonyl-hex-4-en-1-ol (110815-16-2) + 15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (110815-14-0) → 15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (E)-6,6-bis-benzenesulfonyl-hex-4-enyl ester (110815-15-1)

Guidance literature:

With dicyclohexyl-carbodiimide; dmap; Yield given;

DOI:10.1016/S0040-4039(00)85303-4

Reference yield:

15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid (E)-6,6-bis-benzenesulfonyl-hex-4-enyl ester (110815-15-1) → (18E,22E)-21,21-Bis-benzenesulfonyl-16-(tert-butyl-diphenyl-silanyloxy)-17-hydroxy-oxacyclohexacosa-18,22-dien-2-one (110815-17-3)

Guidance literature:

With n-butyllithium; palladium diacetate; triisopropyl phosphite; Product distribution; further catalysts;

DOI:10.1016/S0040-4039(00)85303-4

upstream raw materials:

(E)-6,6-Bis-benzenesulfonyl-hex-4-en-1-ol

15-(tert-Butyl-diphenyl-silanyloxy)-15-(3-vinyl-oxiranyl)-pentadecanoic acid

Downstream raw materials:

(18E,22E)-21,21-Bis-benzenesulfonyl-16-(tert-butyl-diphenyl-silanyloxy)-17-hydroxy-oxacyclohexacosa-18,22-dien-2-one