methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate

Base Information

Chemical Name:methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate
CAS No.:172877-82-6
Molecular Formula:C₁₇H₁₉NO₅
Molecular Weight:317.342
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate

Chemical Property:

Purity/Quality:

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Technology Process of methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate

There total 3 articles about methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 532-32-1
sodium benzoate

: 172877-82-6
methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: oxygen, glucose, MgSO₄, KH₂PO₄, (NH₄)2SO₄, polypropyleneglycol, CaCl₂, FeSO₄, ZnSO₄, CuSO₄, MnSO₄, CoCl₂, H₃BO₄, citric acid, ammonia, phosphoric acid / H₂O / 30 °C / Pseudomonas putida U₁₀₃ presence

2: 95 percent / CH₂Cl₂; ethanol

3: 92 percent / toluene-p-sulfonic acid / 4 h

4: 68 percent / toluene / 6 h / Ambient temperature

With ammonium sulfate; manganese(II) sulfate; potassium dihydrogenphosphate; polypropyleneglycol; (per)acetylperoxyboric acid; D-glucose; phosphoric acid; ammonia; oxygen; magnesium sulfate; toluene-4-sulfonic acid; copper(II) sulfate; iron(II) sulfate; zinc(II) sulfate; citric acid; calcium chloride; In ethanol; dichloromethane; water; toluene;

Reference yield:

: 172877-72-4
(-)-(1S,6R)-methyl 1,6-dihydroxycyclohexa-2,4-dienecarboxylate

: 172877-82-6
methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / toluene-p-sulfonic acid / 4 h

2: 68 percent / toluene / 6 h / Ambient temperature

With toluene-4-sulfonic acid; In toluene;

Reference yield:

: 32359-20-9
(1S,2R)-1,2-dihydroxycyclohexa-3,5-diene-1-carboxylic acid

: 172877-82-6
methyl (1R,2R,3S,6R)-1,2-isopropylidenedioxy-8-phenyl-7-oxa-8-azabicyclo<2.2.2>oct-4-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / CH₂Cl₂; ethanol

2: 92 percent / toluene-p-sulfonic acid / 4 h

3: 68 percent / toluene / 6 h / Ambient temperature

With toluene-4-sulfonic acid; In ethanol; dichloromethane; toluene;