Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside

Base Information

Chemical Name:Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside
CAS No.:87907-34-4
Molecular Formula:C29H31NO7
Molecular Weight:505.568
Hs Code.:
Mol file:87907-34-4.mol

Synonyms:Methyl 3-O-benzyl-4,6-O-benzylidene-N-Cbz-alpha-D-glucosaminide;Methyl 3-O-benzyl-4,6-O-benzylidene-N-Cbz-α-D-glucopyranosaminide;methyl 3-O-benzyl-4,6-O-benzylidene-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside;Methyl 3-O-benzyl-4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-alpha-D-glucopyranoside min. 99%;METHYL2-DEOXY-2-[[(PHENYLMETHOXY)CARBONYL]AMINO]-3-O-(PHENYLMETHYL)-4,6-O-(PHENYLMETHYLENE)-A-D-GLUCOPYRANOSIDE;Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside;Methyl 2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside

Suppliers and Price of Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 6 raw suppliers

Chemical Property of Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside

Chemical Property:

PSA：84.48000
LogP:4.74320

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside

There total 7 articles about Methyl2-deoxy-2-[[(phenylmethoxy)carbonyl]amino]-3-O-(phenylmethyl)-4,6-O-(phenylmethylene)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 100-39-0
benzyl bromide

: 60076-41-7
methyl 4,6-O-benzylidene-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside

: 87907-34-4
methyl 3-O-benzyl-4,6-O-benzylidene-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside

Guidance literature:: With barium hydroxide octahydrate; barium(II) oxide; In N,N-dimethyl-formamide; for 5h;
DOI:10.1016/0008-6215(84)85281-7

Reference yield: 73.0%

: 100-39-0
benzyl bromide

: 60076-41-7,68405-76-5,93000-10-3,99745-45-6
methyl 4,6-O-benzylidene-2-(benzyloxycarbonyl)-amino-2-deoxy-α-D-glucopyranoside

: 87907-34-4,93000-11-4
((2S,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid benzyl ester

Guidance literature:: With potassium hydroxide; In 1,4-dioxane;
DOI:10.1016/S0040-4039(00)85356-3

Reference yield:

: 1078691-95-8
(+)-D-glucosamine hydrochloride

: 87907-34-4
methyl 3-O-benzyl-4,6-O-benzylidene-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: aq. Na₂CO₃

2: HCl

3: CSA / tetrahydrofuran

4: 78 percent / BaO; Ba(OH)2*8H₂O / dimethylformamide

With hydrogenchloride; barium dihydroxide; camphor-10-sulfonic acid; sodium carbonate; barium(II) oxide; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Acylation / 2: Glycosidation / 3: Acetalization / 4: Alkylation;
DOI:10.1016/S0960-894X(99)00550-8