Methyl-azido-2-deoxy-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-acetate

Base Information

Chemical Name:Methyl-azido-2-deoxy-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-acetate
CAS No.:175978-56-0
Molecular Formula:C16H21N3O6
Molecular Weight:351.359
Hs Code.:
Mol file:175978-56-0.mol

Synonyms:methyl 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside;a-D-Gluxopyranoside,methyl 2-azido-2-deoxy-3-O-(phenylmethyl)-6-acetate;

Suppliers and Price of Methyl-azido-2-deoxy-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 7 raw suppliers

Chemical Property of Methyl-azido-2-deoxy-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-acetate

Chemical Property:

PSA：123.97000
LogP:0.99876

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Methyl-azido-2-deoxy-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-acetate

There total 4 articles about Methyl-azido-2-deoxy-3-O-(phenylmethyl)-alpha-D-glucopyranoside6-acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 75-36-5
acetyl chloride

: 175978-55-9
methyl 2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside

: 175978-56-0
methyl 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: With pyridine; at 0 ℃;
DOI:10.1016/0008-6215(95)00346-0

Reference yield:

: 110522-37-7,124579-04-0,128442-04-6,124579-02-8
1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-arabino-hex-1-enitol

: 175978-56-0
methyl 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 57 percent / NaN₃, cerium(IV) ammonium nitrate / acetonitrile / 3 h / -10 °C

2: 76 percent / CsF / acetonitrile / 2 h / 60 °C

3: 100 percent / aq. TFA / CH₂Cl₂ / 4 h / Ambient temperature

4: 92 percent / pyridine / 0 °C

With pyridine; sodium azide; ammonium cerium(IV) nitrate; cesium fluoride; trifluoroacetic acid; In dichloromethane; acetonitrile;
DOI:10.1016/0008-6215(95)00346-0

Reference yield:

: 162678-87-7
Methyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside

: 175978-56-0
methyl 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / aq. TFA / CH₂Cl₂ / 4 h / Ambient temperature

2: 92 percent / pyridine / 0 °C

With pyridine; trifluoroacetic acid; In dichloromethane;
DOI:10.1016/0008-6215(95)00346-0