[(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4

Base Information

Chemical Name:[(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4
CAS No.:344800-64-2
Molecular Formula:BF₄*C₂₇H₁₇F₉NO₂PRe
Molecular Weight:862.408
Hs Code.:

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Chemical Property of [(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4

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Technology Process of [(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4

There total 2 articles about [(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 92269-93-7
[(η(5)-C5H5)Re(NO)(CO)(MeCN)]BF4

: 13406-29-6
tris(para-trifluoromethyl)phenyl phosphine

: 344800-64-2
[(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4

Guidance literature:: In butanone; all manipulations under dry N2 atm.; EtCOMe added to Re complex and the phosphane, refluxed for 46 h; allowed to cool, hexane added, filtered, washed with pentane, dried in vac., elem. anal.;

Reference yield: 44.0%

: 344800-65-3
[(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)]

: nitrosonium tetrafluoroborate

: [(η(5)-C5H5)Re(NO)(CO)2]BF4

: 344800-64-2
[(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4

Guidance literature:: In dichloromethane; all manipulations under dry N2 atm.; complex dissolved in CH2Cl2, cooledto 0°C, NOBF4 added with stirring, allowed to warm; after 30 h solvent was removed by rotary evapn., addn. of THF, ppt. filtered off (dicarbonyl complex sepd.), filtrate concd., hexane added, ppt.filtered off, washed with CH2Cl2/hexane and pentane, dried in vac., ele m. anal.;

Reference yield: 71.0%

: 16940-66-2
sodium tetrahydroborate

: 344800-64-2
[(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4

: 344800-67-5
[(μ5-C5H5)Re(NO)(H)(P(4-C6H4CF3)3)]

: 344800-66-4
[(μ5-C5H5)Re(NO)(CH3)(P(4-C6H4CF3)3)]

Guidance literature:: In tetrahydrofuran; all manipulations under dry N2 atm.; mixt. of complex and NaBH4 in THF was stirred for 2 h; solvent removed, residue dissolved in hexane, slowly concd., ppt. filtered off, dried in vac.; not separated, detected by MS and NMR;