[(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)]

Base Information

Chemical Name:[(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)]
CAS No.:344800-65-3
Molecular Formula:C₂₈H₁₇F₉O₂PRe
Molecular Weight:773.608
Hs Code.:

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Chemical Property of [(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)]

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Technology Process of [(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)]

There total 1 articles about [(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: tricarbonylcyclopentadienylrhenium

: 13406-29-6
tris(para-trifluoromethyl)phenyl phosphine

: 344800-65-3
[(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)]

Guidance literature:: With tetrahydrofuran; In tetrahydrofuran; Irradiation (UV/VIS); all manipulations under dry N2 atm.; quartz tube charged with complex and THF, placed in ice/water bath, irradiated with high pressure Hg lamp, after 3 h lamp turned off, P compd. added; after 72 h solvent removed in vac., hexane added, soln. filtered throughCelite, filtrate slowly concd. by rotary evapn., crystals filtered off, washed with pentane, dried in vac., elem. anal.;

Reference yield: 44.0%

: 344800-65-3
[(μ5-C5H5)Re(CO)2(P(4-C6H4CF3)3)]

: nitrosonium tetrafluoroborate

: [(η(5)-C5H5)Re(NO)(CO)2]BF4

: 344800-64-2
[(μ5-C5H5)Re(NO)(CO)(P(4-C6H4CF3)3)]BF4

Guidance literature:: In dichloromethane; all manipulations under dry N2 atm.; complex dissolved in CH2Cl2, cooledto 0°C, NOBF4 added with stirring, allowed to warm; after 30 h solvent was removed by rotary evapn., addn. of THF, ppt. filtered off (dicarbonyl complex sepd.), filtrate concd., hexane added, ppt.filtered off, washed with CH2Cl2/hexane and pentane, dried in vac., ele m. anal.;