(3Z)-3-benzylidene-1,2-dihydrocyclopenta[b]quinoline

Base Information

Chemical Name:(3Z)-3-benzylidene-1,2-dihydrocyclopenta[b]quinoline
CAS No.:32353-38-1
Molecular Formula:C19H15N
Molecular Weight:257.335
Hs Code.:
NSC Number:239348
DSSTox Substance ID:DTXSID20428520
Mol file:32353-38-1.mol

Synonyms:32353-38-1;(3Z)-3-benzylidene-1,2-dihydrocyclopenta[b]quinoline;AO-840/42717831;NSC239348;DTXSID20428520;YTSWLKWYRVTRMW-VBKFSLOCSA-N;NSC-239348;3-benzylidene-2,3-dihydro-1H-cyclopenta[b]quinoline

Suppliers and Price of (3Z)-3-benzylidene-1,2-dihydrocyclopenta[b]quinoline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (3Z)-3-benzylidene-1,2-dihydrocyclopenta[b]quinoline

Chemical Property:

Vapor Pressure:1.94E-07mmHg at 25°C
Boiling Point:437.3°C at 760 mmHg
Flash Point:193°C
PSA：12.89000
Density:1.204g/cm³
LogP:4.72160
XLogP3:4.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:257.120449483
Heavy Atom Count:20
Complexity:366

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC(=CC2=CC=CC=C2)C3=NC4=CC=CC=C4C=C31
Isomeric SMILES:C1C/C(=C/C2=CC=CC=C2)/C3=NC4=CC=CC=C4C=C31

Technology Process of (3Z)-3-benzylidene-1,2-dihydrocyclopenta[b]quinoline

There total 4 articles about (3Z)-3-benzylidene-1,2-dihydrocyclopenta[b]quinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 5661-06-3
2,3-dihydro-1H-cyclopenta[b]quinoline

: 100-52-7
benzaldehyde

: 32353-38-1
(E)-3-benzylidene-2,3-dihydro-1H-cyclopenta[b]quinoline

Guidance literature:: With indium(III) chloride; In tetrahydrofuran; at 120 ℃; for 24h; Sealed tube;
DOI:10.1016/j.tet.2016.03.004

Reference yield:

: 552-89-6
2-nitro-benzaldehyde

: 32353-38-1
(E)-3-benzylidene-2,3-dihydro-1H-cyclopenta[b]quinoline

Guidance literature:: Multi-step reaction with 3 steps

1: iron; hydrogenchloride / ethanol; water / 0.67 h / 95 °C

2: potassium hydroxide / ethanol; water / 0.5 h / 95 °C

3: indium(III) chloride / tetrahydrofuran / 24 h / 120 °C / Sealed tube

With hydrogenchloride; indium(III) chloride; iron; potassium hydroxide; In tetrahydrofuran; ethanol; water;
DOI:10.1016/j.tet.2016.03.004

Reference yield:

: 529-23-7
o-aminobenzaldehyde

: 32353-38-1
(E)-3-benzylidene-2,3-dihydro-1H-cyclopenta[b]quinoline

Guidance literature:: Multi-step reaction with 2 steps

1: potassium hydroxide / ethanol; water / 0.5 h / 95 °C

2: indium(III) chloride / tetrahydrofuran / 24 h / 120 °C / Sealed tube

With indium(III) chloride; potassium hydroxide; In tetrahydrofuran; ethanol; water;
DOI:10.1016/j.tet.2016.03.004