[5-bromo-15-(4'-N,N-dimethylaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II)

Base Information

Chemical Name:[5-bromo-15-(4'-N,N-dimethylaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II)
CAS No.:713136-04-0
Molecular Formula:C₄₂H₂₈BrN₅Ni
Molecular Weight:741.312
Hs Code.:

Synonyms:

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Chemical Property of [5-bromo-15-(4'-N,N-dimethylaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II)

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Technology Process of [5-bromo-15-(4'-N,N-dimethylaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II)

There total 1 articles about [5-bromo-15-(4'-N,N-dimethylaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 193265-36-0
(5,15-dibromo-10,20-diphenylporphyrinato)nickel(II)

: 17573-94-3,752235-18-0
4-ethynyl-N,N-dimethylaniline

: 713136-04-0
[5-bromo-15-(4'-N,N-dimethylaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II)

Guidance literature:: With Pd(PPh₃)2Cl₂; CuI; Et₃N; In tetrahydrofuran; under N2; Et3N added dropwise to soln. of Ni porphyrin, 4-N,N-dimethylaminophenylethyne, Pd complex and CuI (molar ratio 1:1.8:0.08:0.14) in THF; stirred at 50°C for 12 h; volatiles removed in vac.; purified by chromy. (silica gel, toluene-hexanes); second reddish-green band collected; evapd.;
DOI:10.1016/j.jorganchem.2004.02.007

Reference yield: 45.0%

: 1271-47-2
ferroceneacetylene

: 713136-04-0
[5-bromo-15-(4'-N,N-dimethylaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II)

: 713136-13-1
[5-ferrocenylethynyl-15-(4'-N,N-dimethyaminophenylethynyl)-10,20-diphenylporphyrinato]nickel(II)

Guidance literature:: With Pd(PPh₃)2Cl₂; CuI; Et₃N; In tetrahydrofuran; under N2; Et3N added to mixt. of Ni porphyrin, Fe complex, Pd complex and CuI (molar ratio 1:1.9:0.2:0.11) in THF; stirred at 60°C for 12h; volatiles removed in vac.; purified by chromy. (silica gel, hexanes-CHCl3); green band collected; rotary evapd.;
DOI:10.1016/j.jorganchem.2004.02.007