Diethyl 2-(bromomethyl)malonate

Base Information

Chemical Name:Diethyl 2-(bromomethyl)malonate
CAS No.:34762-17-9
Molecular Formula:C8H13BrO4
Molecular Weight:253.093
Hs Code.:2917190090
DSSTox Substance ID:DTXSID30526723
Nikkaji Number:J191.501K
Wikidata:Q82395467
Mol file:34762-17-9.mol

Synonyms:Diethyl 2-(bromomethyl)malonate;34762-17-9;Diethyl 2-(bromomethyl)propanedioate;Diethyl2-(bromomethyl)malonate;SCHEMBL1669735;DTXSID30526723;Diethyl (bromomethyl)propanedioate;GSFDYMMFCGYFJF-UHFFFAOYSA-N;AKOS015843265;A6098

Suppliers and Price of Diethyl 2-(bromomethyl)malonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
DIETHYL-2-(BROMOMETHYL)MALONATE 95.00%
5MG
$ 504.44

Total 14 raw suppliers

Chemical Property of Diethyl 2-(bromomethyl)malonate

Chemical Property:

Vapor Pressure:0.05mmHg at 25°C
Refractive Index:1.468
Boiling Point:235.444 °C at 760 mmHg
PKA:11.13±0.46(Predicted)
Flash Point:96.193 °C
PSA：52.60000
Density:1.397 g/cm³
LogP:1.12370
XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:7
Exact Mass:251.99972
Heavy Atom Count:13
Complexity:163

Purity/Quality:

97% ^*data from raw suppliers

DIETHYL-2-(BROMOMETHYL)MALONATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(CBr)C(=O)OCC

Technology Process of Diethyl 2-(bromomethyl)malonate

There total 3 articles about Diethyl 2-(bromomethyl)malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 30379-04-5
diethyl ethoxymethylenemalonate

: 34762-17-9
ethyl 3-bromo-2-(ethoxycarbonyl)propionate

Guidance literature:: With hydrogen bromide; In ethanol; for 48h;
DOI:10.1002/hlca.19830660843

Reference yield:

: 3377-20-6,30329-60-3
diethyl methylenemalonate

: 34762-17-9
ethyl 3-bromo-2-(ethoxycarbonyl)propionate

Guidance literature:: With diethyl ether; hydrogen bromide;

Reference yield:

: 996-82-7,34727-00-9,73177-21-6
sodium diethylmalonate

: 34762-17-9
ethyl 3-bromo-2-(ethoxycarbonyl)propionate

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether

2: water; hydrobromic acid

With diethyl ether; water; hydrogen bromide;