tetraphenylantimony 4-methylbenzenesulfonate

Base Information

• Chemical Name: tetraphenylantimony 4-methylbenzenesulfonate
• CAS No.: 104316-53-2
• Molecular Formula: C₇H₇O₃S*C₂₄H₂₀Sb
• Molecular Weight: 601.37
• Mol file: 104316-53-2.mol

Synonyms:

Chemical Property of tetraphenylantimony 4-methylbenzenesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylantimony 4-methylbenzenesulfonate

There total 6 articles about tetraphenylantimony 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

diphenylbismuth 4-methylbenzenesulfonate (108858-14-6) + pentaphenylantimony (2170-05-0) → tetraphenylantimony 4-methylbenzenesulfonate (104316-53-2,481073-75-0) + triphenylbismuthane (603-33-8)

Guidance literature:

In diethyl ether; mixt. of Ph5Sb and Bi sulfonate in ether kept for 48 h at 20°C; ppt. filtered, washed (hexane), dried; ethereal and hexane soln. evapd.,recrystd. from EtOH;

DOI:10.1023/A:1023463212564

Reference yield: 95.0%

phenylbismuth bis(4-methylbenzenesulfonate) (329914-94-5) + pentaphenylantimony (2170-05-0) → diphenylbismuth 4-methylbenzenesulfonate (108858-14-6) + tetraphenylantimony 4-methylbenzenesulfonate (104316-53-2,481073-75-0)

Guidance literature:

In diethyl ether; mixt. of Ph5Sb and Bi sulfonate in ether kept for 48 h at 20°C; concd., extracted (toluene), ppt. filtered, dried; toluene soln. evapd.;

DOI:10.1023/A:1023463212564

Reference yield: 91.6%

triphenylantimony bis(p-toluenesulfonate) + pentaphenylantimony (2170-05-0) → tetraphenylantimony 4-methylbenzenesulfonate (104316-53-2,481073-75-0)

Guidance literature:

In toluene; 100°C, 45 min; cooling, solvent removing, residue re-crystn. (benzene-petroleum ether);

upstream raw materials:

pentaphenylantimony

hypochlorous acid 4-methylbenzene sulfonic anhydride

tetraphenylstibonium hydroxide

toluene-4-sulfonic acid