bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane

Base Information

Chemical Name:bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane
CAS No.:1025023-41-9
Molecular Formula:C₂₃H₂₅IN₄Sn
Molecular Weight:603.093
Hs Code.:

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Chemical Property of bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane

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Technology Process of bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane

There total 1 articles about bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 586956-16-3
bis(3,5-dimethylpyrazol-1-yl)triphenylstannylmethane

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 1025023-41-9
bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane

Guidance literature:: In chloroform; (Ar); addn. dropwise of soln. of I2 in CHCl3 to stirred soln. of Ph3SnCH(3,5-Me2C3HN2)2 in CHCl3 at 10°C; stirring for 1 h at room temp.; removal of solvent under reduced pressure, recrystn. from hot hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.041

Reference yield: 57.0%

: 2637-34-5,73018-10-7
2-Sulfanylpyridine

: 1025023-41-9
bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane

: 1025023-47-5
[bis(3,5-dimethylpyrazol-1-yl)(diphenyl(2-PyS)stannyl)methane]

Guidance literature:: With NaH; In benzene; (Ar); addn. of NaH to soln. of 2-pyridinethiol in benzene at room temp.;stirring for 2 h; addn. of soln. of Ph2SnICH(3,5-Me2C3HN2)2 in benzene; stirring overnight at room temp.; filtration, removal of solvent under reduced pressure, recrystn. from hot hexane, elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.041

Reference yield: 45.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 14040-11-0
tungsten hexacarbonyl

: 1025023-41-9
bis(3,5-dimethylpyrazol-1-yl)(iododiphenylstannyl)methane

: [(bis(3,5-dimethylpyrazol-1-yl)(diphenylstannyl)methane)W(CO)3I]

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); (Ar); irradn. of W(CO)6 in THF for 8 h; addn. of Ph2ISnCH(3,5-Me2-pyrazolyl)2; stirring and heating at reflux for 3 h; removal of solvent under reduced pressure, chromy. on silica gel using CH2Cl2/hexane (3/1 v/v) as eluent; concn. of eluate to dryness; recrystn.from CH2Cl2/hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.041