mer-{1,2-bis(diethylphosphino)ethane}trichloro(dimethylphenylphosphine oxide-κO)vanadium(III)

Base Information

• Chemical Name: mer-{1,2-bis(diethylphosphino)ethane}trichloro(dimethylphenylphosphine oxide-κO)vanadium(III)
• CAS No.: 136244-48-9
• Molecular Formula: C₁₈H₃₅Cl₃OP₃V
• Molecular Weight: 517.697
• Mol file: 136244-48-9.mol

Synonyms:

Chemical Property of mer-{1,2-bis(diethylphosphino)ethane}trichloro(dimethylphenylphosphine oxide-κO)vanadium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-{1,2-bis(diethylphosphino)ethane}trichloro(dimethylphenylphosphine oxide-κO)vanadium(III)

There total 1 articles about mer-{1,2-bis(diethylphosphino)ethane}trichloro(dimethylphenylphosphine oxide-κO)vanadium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III) (136210-98-5) + depe (6411-21-8) → mer-{1,2-bis(diethylphosphino)ethane}trichloro(dimethylphenylphosphine oxide-κO)vanadium(III) (136244-48-9)

Guidance literature:

In toluene; under N2, 1 h stirring, rapid colour change to green; solvent removed in vac., resulting oil dissolved in min. of CH2Cl2, addn. of large excess of hexane, leaving at -20°C for 3 d, elem. anal.;

DOI:10.1039/DT9910001755

upstream raw materials:

trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)

depe