trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)

Base Information

Chemical Name:trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)
CAS No.:136210-98-5
Molecular Formula:C₂₄H₃₃Cl₃OP₃V
Molecular Weight:587.747
Hs Code.:

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Chemical Property of trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)

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Technology Process of trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)

There total 2 articles about trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 7727-18-6
vanadium(V) oxychloride

: 672-66-2
Dimethyl(phenyl)phosphine

: 136210-98-5
trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)

Guidance literature:: In toluene; under N2, to a rapidly stirring soln. of VOCl3 in toluene was added PMe2Ph, colour change from dark red through green to orange, very exothermic reaction, stirring for 1 h, product pptd.; filtration, washing with toluene, then diethyl ether, drying in vac., recrystn. from CH2Cl2 by allowing diethyl ether to diffuse slowly into the soln., elem. anal.;
DOI:10.1039/DT9910001755

Reference yield:

: 7632-51-1
vanadiumtetrachloride

: 672-66-2
Dimethyl(phenyl)phosphine

: 136210-98-5
trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)

Guidance literature:: In hexane; toluene; under Ar: layering of VCl4 soln. with toluene/hexane (1:1); slow addn. of P(CH3)2C6H5;; crystn. after 2 weeks;;
DOI:10.1016/0020-1693(93)03684-3

Reference yield: 81.0%

: 136210-98-5
trans,mer-trichlorobis(dimethylphenylphosphine)(dimethylphenylphosphine oxide-κO)vanadium(III)

: 162586-88-1,136211-02-4
dimethylphenylphosphonium tetrachloro(dimethylphenylphosphine oxide)vanadium

Guidance literature:: With HCl; chlorotrimethylsilane; In tetrahydrofuran; methanol; under N2, 5 equivalent anhydrous HCl in CH3OH, soln. immediately turned to pink and rapidly pptd. the product; elem. anal.;
DOI:10.1039/DT9910001755