C₆₀H₁₁₃F₃O₉Si₅

Base Information

• Chemical Name: C₆₀H₁₁₃F₃O₉Si₅
• CAS No.: 1422463-63-5
• Molecular Formula: C₆₀H₁₁₃F₃O₉Si₅
• Molecular Weight: 1175.97

Synonyms:

Chemical Property of C₆₀H₁₁₃F₃O₉Si₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₀H₁₁₃F₃O₉Si₅

There total 20 articles about C₆₀H₁₁₃F₃O₉Si₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C26H37NO5S → C60H113F3O9Si5 (1422463-63-5)

Guidance literature:

Multi-step reaction with 14 steps

1.1: diisobutylaluminium hydride / dichloromethane / 2 h / -78 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

3.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 20 °C / pH 7

4.2: 1 h / 20 °C / Inert atmosphere

5.1: toluene / 16 h / 112 °C / Inert atmosphere; Sealed tube; High pressure

6.1: sodium hydride / 1,2-dimethoxyethane / 1 h / 20 °C / Inert atmosphere

6.2: 3 h / Inert atmosphere; Reflux

7.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / 1.5 h / -78 °C / Inert atmosphere

8.1: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -78 - -50 °C / Molecular sieve; Inert atmosphere

9.1: sodium bis(2-methoxyethoxy)aluminium dihydride / tetrahydrofuran; toluene / 2.5 h / 0 °C / Inert atmosphere

10.1: triethylamine / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

11.1: water; acetic acid / tetrahydrofuran / 1.5 h / 0 °C

12.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

13.1: lithium diisopropyl amide / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

13.2: 0.08 h / -78 °C / Inert atmosphere

13.3: -78 °C / Inert atmosphere

14.1: dmap / dichloromethane / 0.17 h

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; dmap; L-(+)-diisopropyl tartrate; water; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium diisopropyl amide; In tetrahydrofuran; 1,2-dimethoxyethane; decane; dichloromethane; N,N-dimethyl-formamide; toluene; 4.2: |Dess-Martin Oxidation / 5.1: |Wittig Olefination / 6.1: |Horner-Wadsworth-Emmons Olefination / 6.2: |Horner-Wadsworth-Emmons Olefination / 8.1: |Sharpless Asymmetric Epoxidation / 12.1: |Dess-Martin Oxidation;

DOI:10.1021/jo3026077

Reference yield:

C16H24O3 (1422463-24-8) → C60H113F3O9Si5 (1422463-63-5)

Guidance literature:

Multi-step reaction with 12 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

2.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 20 °C / pH 7

2.2: 1 h / 20 °C / Inert atmosphere

3.1: toluene / 16 h / 112 °C / Inert atmosphere; Sealed tube; High pressure

4.1: sodium hydride / 1,2-dimethoxyethane / 1 h / 20 °C / Inert atmosphere

4.2: 3 h / Inert atmosphere; Reflux

5.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / 1.5 h / -78 °C / Inert atmosphere

6.1: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -78 - -50 °C / Molecular sieve; Inert atmosphere

7.1: sodium bis(2-methoxyethoxy)aluminium dihydride / tetrahydrofuran; toluene / 2.5 h / 0 °C / Inert atmosphere

8.1: triethylamine / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

9.1: water; acetic acid / tetrahydrofuran / 1.5 h / 0 °C

10.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

11.1: lithium diisopropyl amide / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

11.2: 0.08 h / -78 °C / Inert atmosphere

11.3: -78 °C / Inert atmosphere

12.1: dmap / dichloromethane / 0.17 h

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; dmap; L-(+)-diisopropyl tartrate; water; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium diisopropyl amide; In tetrahydrofuran; 1,2-dimethoxyethane; decane; dichloromethane; N,N-dimethyl-formamide; toluene; 2.2: |Dess-Martin Oxidation / 3.1: |Wittig Olefination / 4.1: |Horner-Wadsworth-Emmons Olefination / 4.2: |Horner-Wadsworth-Emmons Olefination / 6.1: |Sharpless Asymmetric Epoxidation / 10.1: |Dess-Martin Oxidation;

DOI:10.1021/jo3026077

Reference yield:

tert-butyldimethylsilyl chloride (18162-48-6) → C60H113F3O9Si5 (1422463-63-5)

Guidance literature:

Multi-step reaction with 12 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

2.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 20 °C / pH 7

2.2: 1 h / 20 °C / Inert atmosphere

3.1: toluene / 16 h / 112 °C / Inert atmosphere; Sealed tube; High pressure

4.1: sodium hydride / 1,2-dimethoxyethane / 1 h / 20 °C / Inert atmosphere

4.2: 3 h / Inert atmosphere; Reflux

5.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / 1.5 h / -78 °C / Inert atmosphere

6.1: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -78 - -50 °C / Molecular sieve; Inert atmosphere

7.1: sodium bis(2-methoxyethoxy)aluminium dihydride / tetrahydrofuran; toluene / 2.5 h / 0 °C / Inert atmosphere

8.1: triethylamine / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

9.1: water; acetic acid / tetrahydrofuran / 1.5 h / 0 °C

10.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

11.1: lithium diisopropyl amide / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

11.2: 0.08 h / -78 °C / Inert atmosphere

11.3: -78 °C / Inert atmosphere

12.1: dmap / dichloromethane / 0.17 h

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; dmap; L-(+)-diisopropyl tartrate; water; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium diisopropyl amide; In tetrahydrofuran; 1,2-dimethoxyethane; decane; dichloromethane; N,N-dimethyl-formamide; toluene; 2.2: |Dess-Martin Oxidation / 3.1: |Wittig Olefination / 4.1: |Horner-Wadsworth-Emmons Olefination / 4.2: |Horner-Wadsworth-Emmons Olefination / 6.1: |Sharpless Asymmetric Epoxidation / 10.1: |Dess-Martin Oxidation;

DOI:10.1021/jo3026077

upstream raw materials:

C₁₆H₂₂O₃

C₁₆H₂₄O₃

tert-butyldimethylsilyl chloride

C₂₂H₃₈O₃Si

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1422463-63-5 C₆₀H₁₁₃F₃O₉Si₅

Send

Send

Metric Ton KG G Pound L ML

Send

Send