<1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

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Chemical Name:<1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene
CAS No.:124462-97-1
Molecular Formula:C₃₄H₅₈O₄
Molecular Weight:530.832
Hs Code.:

<1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

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Chemical Property of <1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

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Technology Process of <1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

There total 12 articles about <1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 124462-96-0,124579-42-6
<1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(-)-1-<6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-2'-hydroxy-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

: 108-24-7
acetic anhydride

: 124462-97-1,124579-43-7
<1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

Guidance literature:: With pyridine; dmap; for 12h; Ambient temperature;

Reference yield:

: 38419-75-9
(1R,2R,4aS,8aS)-1-(2-hydroxyethyl)-2,5,5,8a-tetramethyl-decahydronaphthalen-2-ol

: 124462-97-1,124579-43-7
<1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

Guidance literature:: Multi-step reaction with 6 steps

1: 99 percent / pyridine / CH₂Cl₂ / 12 h / Ambient temperature

2: 84 percent / diisopropylethylamine / 1,2-dichloro-ethane / 12 h / Ambient temperature

3: 98 percent / K₂CO₃ / methanol / 12 h / Ambient temperature

4: 96 percent / pyridinium dichromate / CH₂Cl₂ / 2 h / Ambient temperature

6: 81 percent / pyridine, 4-(dimethylamino)pyridine / 12 h / Ambient temperature

With pyridine; dmap; dipyridinium dichromate; potassium carbonate; N-ethyl-N,N-diisopropylamine; In methanol; dichloromethane; 1,2-dichloro-ethane;

Reference yield:

: 124177-09-9
ethyl (1R,3S)-3-hydroxy-2,2-dimethyl-6-methylenecyclohexaneacetate

: 124462-97-1,124579-43-7
<1R<2'RS,3'E(1'')R>,2R,4aS,8aS>-(+)-1-<2'-acetoxy-6'-(2'',2''-dimethyl-6''-methylenecyclohexyl)-4'-methyl-3'-hexenyl>-1,2,3,4,4a,5,6,7,8,8a-decahydro-2-(methoxymethyloxy)-2,5,5,8a-tetramethylnaphthalene

Guidance literature:: Multi-step reaction with 7 steps

1: 100 percent / LiAlH₄ / CH₂Cl₂ / 20 h / Ambient temperature

2: 98 percent / NEt₃ / CH₂Cl₂ / 20 h / Ambient temperature

3: 1. n-butyllithium, N,N,N',N'-tetramethylethylendiamine / 1. n-hexane, 1,2-dimethoxyethane, 2 h, room temperature 2. 20 h, room temperature

5: 78 percent / K₂CO₃ / methanol / 12 h / Ambient temperature

7: 81 percent / pyridine, 4-(dimethylamino)pyridine / 12 h / Ambient temperature

With pyridine; dmap; lithium aluminium tetrahydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; potassium carbonate; triethylamine; In methanol; dichloromethane;