Technology Process of (3S)-3-Benzyloxy-4-(1,4-dihydroxy-9,10-anthraquinon-2-yl)-3-methylbutanal
There total 6 articles about (3S)-3-Benzyloxy-4-(1,4-dihydroxy-9,10-anthraquinon-2-yl)-3-methylbutanal which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium periodate;
In
dichloromethane; water;
at 25 ℃;
for 20h;
Yield given;
DOI:10.1055/s-1991-26442
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1) NaH / 1) DMF, -20 deg C, 2 h, 2) -20 deg C, 4 h
2: 75 percent / DIBAL-H / toluene / 3 h / -78 °C
3: 1) piperidine, glac. AcOH, 2) O2 / 1) i-PrOH, 25 deg C, 24 h, 2) 25 deg C, 30 min
4: 7.22 g / 90percent AcOH / 20 h / 25 °C
5: NaIO4 / CH2Cl2; H2O / 20 h / 25 °C
With
piperidine; sodium periodate; oxygen; sodium hydride; diisobutylaluminium hydride; acetic acid;
In
dichloromethane; water; toluene;
DOI:10.1055/s-1991-26442
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1) NaH / 1) DMF, -20 deg C, 2 h, 2) -20 deg C, 4 h
2: 75 percent / DIBAL-H / toluene / 3 h / -78 °C
3: 1) piperidine, glac. AcOH, 2) O2 / 1) i-PrOH, 25 deg C, 24 h, 2) 25 deg C, 30 min
4: 7.22 g / 90percent AcOH / 20 h / 25 °C
5: NaIO4 / CH2Cl2; H2O / 20 h / 25 °C
With
piperidine; sodium periodate; oxygen; sodium hydride; diisobutylaluminium hydride; acetic acid;
In
dichloromethane; water; toluene;
DOI:10.1055/s-1991-26442
