(2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide

Base Information

Chemical Name:(2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide
CAS No.:132791-36-7
Molecular Formula:BrH*C₄₅H₅₈N₂O₁₈S₂
Molecular Weight:1060
Hs Code.:

(2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide

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Chemical Property of (2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide

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Technology Process of (2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide

There total 15 articles about (2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-1-[(2S,5S,6S,11S,14S,15S)-6,15-Bis-benzyloxymethyl-11-((R)-1,2-dihydroxy-ethyl)-5,14-bis-hydroxymethyl-1,4,7,10,13,16-hexaoxa-cyclooctadec-2-yl]-ethane-1,2-diol

: 132791-36-7
(2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide

Guidance literature:: Multi-step reaction with 14 steps

1: TsOH

2: pyridine

3: NaH / dimethylsulfoxide

4: 1N HCl / tetrahydrofuran

5: NaIO₄, aq. NaHCO₃ / tetrahydrofuran

6: PDC / dimethylformamide

7: diethyl ether

8: H₂ / Pd/C / methanol

9: pyridine

10: tetrahydrofuran

11: K₂CO₃ / methanol

12: 1N NaOH / tetrahydrofuran

13: NaH / tetrahydrofuran

14: TEA / CH₂Cl₂

With pyridine; hydrogenchloride; sodium hydroxide; sodium periodate; dipyridinium dichromate; TEA; hydrogen; sodium hydride; sodium hydrogencarbonate; potassium carbonate; toluene-4-sulfonic acid; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)98026-2

Reference yield:

: [(2S,3S,8S,11S,12S,17S)-3,12-Bis-benzyloxymethyl-8,17-bis-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-11-hydroxymethyl-1,4,7,10,13,16-hexaoxa-cyclooctadec-2-yl]-methanol

: 132791-36-7
(2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide

Guidance literature:: Multi-step reaction with 13 steps

1: pyridine

2: NaH / dimethylsulfoxide

3: 1N HCl / tetrahydrofuran

4: NaIO₄, aq. NaHCO₃ / tetrahydrofuran

5: PDC / dimethylformamide

6: diethyl ether

7: H₂ / Pd/C / methanol

8: pyridine

9: tetrahydrofuran

10: K₂CO₃ / methanol

11: 1N NaOH / tetrahydrofuran

12: NaH / tetrahydrofuran

13: TEA / CH₂Cl₂

With pyridine; hydrogenchloride; sodium hydroxide; sodium periodate; dipyridinium dichromate; TEA; hydrogen; sodium hydride; sodium hydrogencarbonate; potassium carbonate; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)98026-2

Reference yield:

: (2S,5S,6S,11S,14S,15S)-6,15-Bis-benzyloxymethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarbaldehyde

: 132791-36-7
(2S,5S,6R,11S,14S,15R)-6-(2-Amino-propionylsulfanylmethyl)-15-(2-benzyloxycarbonylamino-acetylsulfanylmethyl)-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid; hydrobromide

Guidance literature:: Multi-step reaction with 9 steps

1: PDC / dimethylformamide

2: diethyl ether

3: H₂ / Pd/C / methanol

4: pyridine

5: tetrahydrofuran

6: K₂CO₃ / methanol

7: 1N NaOH / tetrahydrofuran

8: NaH / tetrahydrofuran

9: TEA / CH₂Cl₂

With pyridine; sodium hydroxide; dipyridinium dichromate; TEA; hydrogen; sodium hydride; potassium carbonate; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)98026-2