(2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester

Base Information

Chemical Name:(2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester
CAS No.:132791-35-6
Molecular Formula:C₃₄H₄₈O₁₄S₂
Molecular Weight:744.879
Hs Code.:

(2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester

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Chemical Property of (2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester

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Technology Process of (2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester

There total 11 articles about (2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-1-[(2S,5S,6S,11S,14S,15S)-6,15-Bis-benzyloxymethyl-11-((R)-1,2-dihydroxy-ethyl)-5,14-bis-hydroxymethyl-1,4,7,10,13,16-hexaoxa-cyclooctadec-2-yl]-ethane-1,2-diol

: 132791-35-6
(2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: TsOH

2: pyridine

3: NaH / dimethylsulfoxide

4: 1N HCl / tetrahydrofuran

5: NaIO₄, aq. NaHCO₃ / tetrahydrofuran

6: PDC / dimethylformamide

7: diethyl ether

8: H₂ / Pd/C / methanol

9: pyridine

10: tetrahydrofuran

11: K₂CO₃ / methanol

With pyridine; hydrogenchloride; sodium periodate; dipyridinium dichromate; hydrogen; sodium hydride; sodium hydrogencarbonate; potassium carbonate; toluene-4-sulfonic acid; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)98026-2

Reference yield:

: [(2S,3S,8S,11S,12S,17S)-3,12-Bis-benzyloxymethyl-8,17-bis-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-11-hydroxymethyl-1,4,7,10,13,16-hexaoxa-cyclooctadec-2-yl]-methanol

: 132791-35-6
(2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester

Guidance literature:: Multi-step reaction with 10 steps

1: pyridine

2: NaH / dimethylsulfoxide

3: 1N HCl / tetrahydrofuran

4: NaIO₄, aq. NaHCO₃ / tetrahydrofuran

5: PDC / dimethylformamide

6: diethyl ether

7: H₂ / Pd/C / methanol

8: pyridine

9: tetrahydrofuran

10: K₂CO₃ / methanol

With pyridine; hydrogenchloride; sodium periodate; dipyridinium dichromate; hydrogen; sodium hydride; sodium hydrogencarbonate; potassium carbonate; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)98026-2

Reference yield:

: (2S,5S,6S,11S,14S,15S)-6,15-Bis-benzyloxymethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarbaldehyde

: 132791-35-6
(2S,5S,6R,11S,14S,15R)-6,15-Bis-mercaptomethyl-5,14-bis-(2-methoxy-phenoxymethyl)-1,4,7,10,13,16-hexaoxa-cyclooctadecane-2,11-dicarboxylic acid dimethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: PDC / dimethylformamide

2: diethyl ether

3: H₂ / Pd/C / methanol

4: pyridine

5: tetrahydrofuran

6: K₂CO₃ / methanol

With pyridine; dipyridinium dichromate; hydrogen; potassium carbonate; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)98026-2