Phosphinodithioic acid, P,P-bis[2-(trifluoromethyl)phenyl]-

Base Information

• Chemical Name: Phosphinodithioic acid, P,P-bis[2-(trifluoromethyl)phenyl]-
• CAS No.: 930765-00-7
• Molecular Formula: C₁₄H₉F₆PS₂
• Molecular Weight: 386.322
• Mol file: 930765-00-7.mol

Synonyms:Phosphinodithioic acid, P,P-bis[2-(trifluoromethyl)phenyl]-

Chemical Property of Phosphinodithioic acid, P,P-bis[2-(trifluoromethyl)phenyl]-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phosphinodithioic acid, P,P-bis[2-(trifluoromethyl)phenyl]-

There total 2 articles about Phosphinodithioic acid, P,P-bis[2-(trifluoromethyl)phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C28H16F12NiP2S4 → bis(o-trifluoromethylphenyl)dithiophosphinic acid (930765-00-7)

Guidance literature:

With hydrogenchloride; In water; at 20 ℃;

DOI:10.1021/acs.inorgchem.8b01635

Reference yield:

C14H8ClF6PS → bis(o-trifluoromethylphenyl)dithiophosphinic acid (930765-00-7)

Guidance literature:

With sodium hydrogen sulfide; In diethyl ether; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.8b01635

Reference yield: 70.0%

bis(o-trifluoromethylphenyl)dithiophosphinic acid (930765-00-7) + nickel dichloride (83864-14-6) → bis[bis(o-trifluoromethylphenyl)dithiophosphinato]nickel(II) (1384253-23-9)

Guidance literature:

In ethanol; water; soln. ligand in EtOH was added to soln. NiCl2 in water, stirred at room temp. for 3 h; soln. was filtered, washed with water and EtOH and allowed to evaporate in air, residue was dissolved in CH2Cl2-hexane (8:1), slow evapn.; elem.anal.;

DOI:10.1021/ic3001587

Downstream raw materials:

bis(o-trifluoromethylphenyl)dithiophosphinic methyl ester

bis[bis(o-trifluoromethylphenyl)dithiophosphinato]nickel(II)