cyclohexanamine

Base Information

• Chemical Name: cyclohexanamine
• CAS No.: 157973-60-9
• Molecular Formula: C6H13N
• Molecular Weight: 99.17
• Mol file: 157973-60-9.mol

Synonyms:CYCLOHEXANAMINE

Chemical Property of cyclohexanamine

Chemical Property:

• Melting Point: -17.7oC
• Boiling Point: 134.5oC at 760 mm Hg
• PSA: 26.02000
• LogP: 1.97810

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cyclohexanamine

There total 432 articles about cyclohexanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.4%

aniline (62-53-3) → N-phenyl-2-cyclohexylamine (1821-36-9) + cyclohexylamine (108-91-8,157973-60-9) + N-cyclohexyl-cyclohexanamine (101-83-7)

Guidance literature:

aluminum oxide; ruthenium; at 170 ℃; for 2.5h; Product distribution; Mechanism; investigation of the hydrogenation of aniline with various hydrogenation catalysts in the presence and abscence of the fused salts;

Reference yield:

cyclohexanol (108-93-0) + phenol (108-95-2,27073-41-2) → N-phenyl-2-cyclohexylamine (1821-36-9) + cyclohexylamine (108-91-8,157973-60-9) + aniline (62-53-3) + N-cyclohexyl-cyclohexanamine (101-83-7)

Guidance literature:

With ammonia; palladium on activated charcoal; at 250 ℃; for 3h; Product distribution; Effect of catalyst (Ru, Rh, Pt on C), reaction time, temperature, amount of ammonia, composition of reaction mixture.;

DOI:10.1246/bcsj.58.1551

Reference yield:

Nitrosobenzene (586-96-9) → N-phenyl-2-cyclohexylamine (1821-36-9) + cyclohexylamine (108-91-8,157973-60-9)

Guidance literature:

With formic acid; palladium on activated charcoal; In methanol; for 70h; Ambient temperature;

DOI:10.1016/S0040-4039(00)60800-6

upstream raw materials:

cyclohexanone-oxime

m-nitrobromobenzene

cyclohexanone N-cyclohexylimine

cyclohexanone

Downstream raw materials:

1-cyclohexyl-2,5-dimethyl-pyrrolidine

N,N'-di-cyclohexylformamidine

selenophene-2-carbaldehyde-cyclohexylimine

N-cyclohexylisonicotinamide

Refernces

• 1、 Chaudhari, Chandan,Sato, Katsutoshi,Ikeda, Yasuyuki,Terada, Kenji,Abe, Naoya,Nagaoka, Katsutoshi. "One-pot synthesis of cyclohexylamine and: N -aryl pyrroles via hydrogenation of nitroarenes over the Pd0.5Ru0.5-PVP catalyst". supporting information. p. 9743 - 9746. Retrieved 2021/06/15.
• 2、 Unglaube, Felix,Kreyenschulte, Carsten Robert,Mejía, Esteban. "Development and Application of Efficient Ag-based Hydrogenation Catalysts Prepared from Rice Husk Waste". . p. 2583 - 2591. Retrieved 2021/04/09.