(4R,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]

Base Information

Chemical Name:(4R,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]
CAS No.:86348-34-7
Molecular Formula:C₃₁H₃₆O₅S
Molecular Weight:520.69
Hs Code.:

Synonyms:

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Chemical Property of (4R,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]

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Technology Process of (4R,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]

There total 42 articles about (4R,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 128990-34-1
(E)-4-(benzhydryloxy)but-2-enal

: 86348-34-7,86363-80-6,86363-81-7,86363-82-8
(4S,5S,4'S,5'S)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]

Guidance literature:: Multi-step reaction with 12 steps

1: 100 percent / NaBH₄ / methanol / 3 h / -20 - -10 °C

2: 92 percent / t-BuOCl, L-(+)-diisopropyl tartrate*Ti(OiPr)4 / CH₂Cl₂ / -20 °C

3: 71 percent / 0.5N NaOH / 2-methyl-propan-2-ol / Heating

4: POCl₃ / CH₂Cl₂ / Ambient temperature

5: m-chloroperoxybenzoic acid / CH₂Cl₂ / -78 °C

6: NaOAc / 8 h / Heating

7: 91 percent / diisobutylaluminum hydride / CH₂Cl₂; hexane / 0.5 h / -78 °C

8: 88 percent / benzene / Ambient temperature

9: 91 percent / NaBH₄ / methanol / -20 - -10 °C

10: 76 percent / t-BuOCl, L-(+)-diisopropyl tartrate, Ti(OiPr)4 / CH₂Cl₂ / -20 °C

11: 0.5N NaOH / 2-methyl-propan-2-ol / Heating

12: d-10-Camphersulfonic acid / CH₂Cl₂ / Ambient temperature

With titanium(IV) isopropylate; sodium hydroxide; sodium tetrahydroborate; tert-butylhypochlorite; L-(+)-diisopropyl tartrate; L-(+)-diisopropyl tartrate*Ti(OiPr)4; sodium acetate; diisobutylaluminium hydride; (+)-10-camphorsulfonic acid; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In methanol; hexane; dichloromethane; tert-butyl alcohol; benzene;
DOI:10.1016/S0040-4020(01)97596-9

Reference yield:

: 128990-34-1
(E)-4-(benzhydryloxy)but-2-enal

: 86348-34-7,86363-80-6,86363-81-7,86363-82-8
(4R,5S,4'S,5'S)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]

Guidance literature:: Multi-step reaction with 12 steps

1: 100 percent / NaBH₄ / methanol / 3 h / -20 - -10 °C

2: 92 percent / t-BuOCl, L-(+)-diisopropyl tartrate*Ti(OiPr)4 / CH₂Cl₂ / -20 °C

3: 71 percent / 0.5N NaOH / 2-methyl-propan-2-ol / Heating

4: POCl₃ / CH₂Cl₂ / Ambient temperature

5: m-chloroperoxybenzoic acid / CH₂Cl₂ / -78 °C

6: NaOAc / 8 h / Heating

7: 100 percent / K₂CO₃ / methanol / Ambient temperature

8: 91 percent / benzene / Ambient temperature

9: NaBH₄ / methanol / -20 - -10 °C

10: 71 percent / t-BuOCl, L-(+)-diisopropyl tartrate, Ti(OiPr)4 / CH₂Cl₂ / -20 °C

11: 0.5N NaOH / 2-methyl-propan-2-ol / Heating

12: d-10-Camphersulfonic acid / CH₂Cl₂ / Ambient temperature

With titanium(IV) isopropylate; sodium hydroxide; sodium tetrahydroborate; tert-butylhypochlorite; L-(+)-diisopropyl tartrate; L-(+)-diisopropyl tartrate*Ti(OiPr)4; sodium acetate; potassium carbonate; (+)-10-camphorsulfonic acid; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In methanol; dichloromethane; tert-butyl alcohol; benzene;
DOI:10.1016/S0040-4020(01)97596-9

Reference yield:

: 128990-34-1
(E)-4-(benzhydryloxy)but-2-enal

: 86348-34-7,86363-80-6,86363-81-7,86363-82-8
(4R,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]

Guidance literature:: Multi-step reaction with 12 steps

1: 100 percent / NaBH₄ / methanol / 3 h / -20 - -10 °C

2: 92 percent / t-BuOCl, L-(+)-diisopropyl tartrate*Ti(OiPr)4 / CH₂Cl₂ / -20 °C

3: 71 percent / 0.5N NaOH / 2-methyl-propan-2-ol / Heating

4: POCl₃ / CH₂Cl₂ / Ambient temperature

5: m-chloroperoxybenzoic acid / CH₂Cl₂ / -78 °C

6: NaOAc / 8 h / Heating

7: 100 percent / K₂CO₃ / methanol / Ambient temperature

8: 91 percent / benzene / Ambient temperature

9: NaBH₄ / methanol / -20 - -10 °C

10: 73 percent / t-BuOCl, D-(-)-diisopropyl tartrate, Ti(OiPr)4 / CH₂Cl₂ / -20 °C

11: 0.5N NaOH / 2-methyl-propan-2-ol / Heating

12: d-10-Camphersulfonic acid / CH₂Cl₂ / Ambient temperature

With titanium(IV) isopropylate; sodium hydroxide; sodium tetrahydroborate; tert-butylhypochlorite; L-(+)-diisopropyl tartrate*Ti(OiPr)4; sodium acetate; potassium carbonate; D-(-)-diisopropyl tartrate; (+)-10-camphorsulfonic acid; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In methanol; dichloromethane; tert-butyl alcohol; benzene;
DOI:10.1016/S0040-4020(01)97596-9