[RuCH3(η5-C5H5)(PPh2(2-MeC6H4))2]

Base Information

• Chemical Name: [RuCH3(η5-C5H5)(PPh2(2-MeC6H4))2]
• CAS No.: 332355-84-7
• Molecular Formula: C₄₄H₄₂P₂Ru
• Molecular Weight: 733.835
• Mol file: 332355-84-7.mol

Synonyms:

Chemical Property of [RuCH3(η5-C5H5)(PPh2(2-MeC6H4))2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [RuCH3(η5-C5H5)(PPh2(2-MeC6H4))2]

There total 1 articles about [RuCH3(η5-C5H5)(PPh2(2-MeC6H4))2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[(η5-C5H5)Ru(P(C6H5)2(2-CH3-C6H4))2Cl] (252894-17-0) + methylmagnesium bromide (75-16-1) → [RuCH3(η5-C5H5)(PPh2(2-MeC6H4))2] (332355-84-7)

Guidance literature:

In diethyl ether; toluene; CH3MgBr in diethyl ether was added dropwise to a toluene-soln. of complex at -40°C, the mixt. was allowed to attain room temp. and stirred for 15 min (Ar); filtered, solvent was removed, pentane was added, ppt. was filtered, recrystd. from toluene-heptane and dried under reduced pressure; elem. anal.;

DOI:10.1016/S0022-328X(00)00675-6

Reference yield: 75.0%

[RuCH3(η5-C5H5)(PPh2(2-MeC6H4))2] (332355-84-7) → C5H5Ru(P(C6H5)2C6H4CH3)(P(C6H5)2C6H4CH2) (332355-86-9)

Guidance literature:

In toluene; byproducts: CH4; a soln. in toluene was heated at 70°C for 30 min (Ar); the solvent was eliminated, oily residue was treated with pentane, ppt. was filtered, recrystd. from toluene-heptane, dried under reduced pressure; elem. anal.;

DOI:10.1016/S0022-328X(00)00675-6

upstream raw materials:

[(η5-C5H5)Ru(P(C6H5)2(2-CH3-C6H4))2Cl]

methylmagnesium bromide

Downstream raw materials:

C₅H₅Ru(P(C₆H₅)2C₆H₄CH₃)(P(C₆H₅)2C₆H₄CH₂)