Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I)

Base Information

• Chemical Name: Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I)
• CAS No.: 385815-83-8
• Molecular Formula: C21H12AuClF9P
• Molecular Weight: 698.705
• DSSTox Substance ID: DTXSID30465663
• Mol file: 385815-83-8.mol

Synonyms:Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I);385815-83-8;chlorogold;tris[4-(trifluoromethyl)phenyl]phosphane;chlorogold,tris[4-(trifluoromethyl)phenyl]phosphane;SCHEMBL19514107;DTXSID30465663;AMY11759;Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I), 99%

Chemical Property of Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I)

Chemical Property:

• Vapor Pressure: 1.01E-05mmHg at 25°C
• Boiling Point: 382.8°C at 760 mmHg
• Flash Point: 185.3°C
• PSA: 13.59000
• LogP: 3.50270
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 3
• Exact Mass: 697.988714
• Heavy Atom Count: 33
• Complexity: 480

Purity/Quality:

98% ^*data from raw suppliers

Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I) 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC(=CC=C1C(F)(F)F)P(C2=CC=C(C=C2)C(F)(F)F)C3=CC=C(C=C3)C(F)(F)F.Cl[Au]
• Uses: Gold Catalysts — 21st Century ′Gold Rush′

Technology Process of Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I)

There total 8 articles about Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + tris(para-trifluoromethyl)phenyl phosphine (13406-29-6) → [tris(para(trifluoromethyl)phenyl)phosphine]gold(I) chloride (385815-83-8)

Guidance literature:

In dichloromethane; at 20 ℃; Darkness;

DOI:10.1002/adsc.202101113

Reference yield: 87.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + tris(para-trifluoromethyl)phenyl phosphine (13406-29-6) → [tris(para(trifluoromethyl)phenyl)phosphine]gold(I) chloride (385815-83-8)

Guidance literature:

In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jacs.7b06668

Reference yield: 85.0%

hydrogen tetrachloroaurate(III) tetrahydrate (1303-50-0,27988-77-8) + tris(para-trifluoromethyl)phenyl phosphine (13406-29-6) → [tris(para(trifluoromethyl)phenyl)phosphine]gold(I) chloride (385815-83-8)

Guidance literature:

With β-thiodiglucol; In methanol; dichloromethane; water; under N2 or Ar using Schlenk techniques; in the dark; soln. of HAuCl4*4H2O dissolved in H2O/MeOH; cooled; soln. of β-thiodiglucol in MeOH added with stirring; soln. of org. ligand in MeOH/CH2Cl2 added; mixt. stirred overnight; MeOH added; solvent removed (vac.); recrystd. (CH2Cl2/hexane); dried (vac.);

DOI:10.1016/S0020-1693(01)00543-6

upstream raw materials:

hydrogen tetrachloroaurate(III) tetrahydrate

tris(para-trifluoromethyl)phenyl phosphine

(tetrahydrothiophene)gold(I) chloride

chloro(dimethylsulfide) gold(I)

Downstream raw materials:

(p-F₃CC₆H₄)3PAuSC₆H₅

tris(p-trifluoromethylphenyl)phosphine gold bis(trifluoromethanesulfonyl)imidate