1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one

Base Information

Chemical Name:1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one
CAS No.:121192-17-4
Molecular Formula:C₂₇H₃₄O₇S
Molecular Weight:502.629
Hs Code.:

1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one

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Chemical Property of 1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one

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Technology Process of 1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one

There total 9 articles about 1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 487-51-4
4-carbethoxy-3-methyl-2-cyclohexen-1-one

: 121192-17-4
1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / p-toluenesulfonic acid / benzene / 12 h / Heating

2: butyllithium / 1.) THF, 0 deg C, 1 h, 2.) THF, 1 h

3: 1.) NaH, 2.) NaI / 1.) THF, 3 h, 2.) THF, 12 h

With n-butyllithium; sodium hydride; toluene-4-sulfonic acid; sodium iodide; In benzene;
DOI:10.1021/jo00275a048

Reference yield:

: 19719-88-1
ethyl 3-<2-<2-(ethoxycarbonyl)ethyl><1,3>dioxolan-2-yl>propionate

: 121192-17-4
1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one

Guidance literature:: Multi-step reaction with 6 steps

1: 73 percent / EtONa / 1,2-dimethoxy-ethane / 48 h / Ambient temperature

2: 1.) NaH / 1.) ether, reflux, 2 h, 2.) ether, RT, overnight

3: 1.) copper(I) iodide, LiBr / 1.) ether, 0 deg C, 15 min, 2.) ether, -10 deg C, 12 h

4: 86 percent / LiAlH₄ / diethyl ether / 4 h / Ambient temperature

5: 83 percent / LiCl, collidine, methanesulfonyl chloride / dimethylformamide / 5 h / 0 °C

6: 1.) NaH, 2.) NaI / 1.) THF, 3 h, 2.) THF, 12 h

With 2,3,5-trimethyl-pyridine; copper(l) iodide; lithium aluminium tetrahydride; sodium ethanolate; sodium hydride; methanesulfonyl chloride; sodium iodide; lithium chloride; lithium bromide; In 1,2-dimethoxyethane; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00275a048

Reference yield:

: 76379-88-9
8-Methyl-1,4-dioxa-spiro[4.5]dec-7-ene-7-carboxylic acid ethyl ester

: 121192-17-4
1-(4,4-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-3-(5,5-(ethylenedioxy)-2-methyl-1-cyclohexenyl)-2-(phenylsulphonyl)-2-(phenylsulfonyl)propan-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / LiAlH₄ / diethyl ether / 4 h / Ambient temperature

2: 83 percent / LiCl, collidine, methanesulfonyl chloride / dimethylformamide / 5 h / 0 °C

3: 1.) NaH, 2.) NaI / 1.) THF, 3 h, 2.) THF, 12 h

With 2,3,5-trimethyl-pyridine; lithium aluminium tetrahydride; sodium hydride; methanesulfonyl chloride; sodium iodide; lithium chloride; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00275a048