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487-51-4

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487-51-4 Usage

Purification Methods

Dissolve the ester in ether, shake with solid K2CO3, aqueous saturated NaHCO3, dry (MgSO4) and distil it. The semicarbazone has m 165-167o (169o). [Smith & Rouault J Am Chem Soc 65 631 1943, Beilstein 10 H 631, 10 I 300, 10 III 2899, 10 IV 2666.]

Check Digit Verification of cas no

The CAS Registry Mumber 487-51-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,8 and 7 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 487-51:
(5*4)+(4*8)+(3*7)+(2*5)+(1*1)=84
84 % 10 = 4
So 487-51-4 is a valid CAS Registry Number.
InChI:InChI=1/C10H14O3/c1-3-13-10(12)9-5-4-8(11)6-7(9)2/h6,9H,3-5H2,1-2H3

487-51-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Ethyl 2-methyl-4-oxo-2-cyclohexenecarboxylate

1.2 Other means of identification

Product number -
Other names ethyl 2-methyl-4-oxocyclohex-2-ene-1-carboxylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:487-51-4 SDS

487-51-4Relevant articles and documents

Palladium-Catalyzed Tandem γ-Arylation/Aromatization of Cyclohex-2-En-1-One Derivatives: A Route to 3,4-Dihydroanthracen-1(2H)-Ones

Feng, Chen-Guo,Fu, Jian-Guo,Lin, Guo-Qiang,Song, Yi-Kang,Xu, Si-Yu,Zhang, Shu-Sheng

supporting information, p. 3001 - 3005 (2021/05/07)

An intramolecular palladium-catalyzed tandem γ-arylation/aromatization reaction of cyclohex-2-en-1-one derivatives was developed. This work provides a simple and efficient approach for the construction of substituted 3,4-dihydroanthracen-1(2H)-ones in good yields with a broad substrate scope. (Figure presented.).

High-yielding synthesis of Nefopam analogues (functionalized benzoxazocines) by sequential one-pot cascade operations

Ramachary, Dhevalapally B.,Narayana, Vidadala V.,Prasad, M. Shiva,Ramakumar, Kinthada

body text, p. 3372 - 3378 (2010/01/06)

An efficient amine-/ruthenium-catalyzed three-step process for the synthesis of Nefopam analogues was achieved through combinations of cascade enamine amination/iso-aromatization/allylation and diene or enyne metathesis as key steps starting from functionalized Hagemann's esters. In this communication, we discovered the application of ruthenium-catalysis on olefins containing free amines without in situ formation of salts.

Oxidative deprotection of oximes using pyridinium fluorochromate and hydrogen peroxide

Ganguly,Sukai,De,De

, p. 1607 - 1612 (2007/10/03)

A simple convenient procedure of oxidative deoximation has been developed using pyridinium fluorochromate (PFC), in combination with 30% hydrogen peroxide. The method has been found to be effective for a wide range of aliphatic and aromatic oximes, and may be used for selective cleavage of aldoximes in the presence of ketoximes.

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