4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl

Base Information

• Chemical Name: 4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl
• CAS No.: 111221-04-6
• Molecular Formula: C₄₀H₄₈N₂O₆
• Molecular Weight: 652.831
• Mol file: 111221-04-6.mol

Synonyms:

Chemical Property of 4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl

There total 6 articles about 4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-Iodotoluene (625-95-6) → 4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl (111221-04-6)

Guidance literature:

Multi-step reaction with 5 steps

1: 76.3 g / aluminium chloride / 0.25 h

2: 93 percent / copper(I) t-butoxide/pyridine / 1,2-dimethoxy-ethane / 20 h / 70 °C

3: 0.43 mg / sodium sulphide nonahydrate/sodium hydrogen carbonate / H₂O; dioxane / 80 - 100 °C

4: 0.48 g / 3-methyl-butyl nitrite/di-iodomethane / 1.) room temp., 20 h; 2.) 75 deg C, 1 h

5: 220 mg / copper(I) chloride / 1,2-dimethoxy-ethane / 24 h / 70 °C

With pyridine; sodium sulfide; diiodomethane; copper (I) tert-butoxide; sodium hydrogencarbonate; copper(l) chloride; isopentyl nitrite; aluminium trichloride; In 1,4-dioxane; 1,2-dimethoxyethane; water;

Reference yield:

2,2',4,4'-tetranitro-1,1'-biphenyl (1820-59-3) → 4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl (111221-04-6)

Guidance literature:

Multi-step reaction with 5 steps

1: 3.1 g / copper(I) t-butoxide/pyridine / 1,2-dimethoxy-ethane / 15 h / 80 °C

2: 82 percent / aluminium chloride

3: 0.43 mg / sodium sulphide nonahydrate/sodium hydrogen carbonate / H₂O; dioxane / 80 - 100 °C

4: 0.48 g / 3-methyl-butyl nitrite/di-iodomethane / 1.) room temp., 20 h; 2.) 75 deg C, 1 h

5: 220 mg / copper(I) chloride / 1,2-dimethoxy-ethane / 24 h / 70 °C

With pyridine; sodium sulfide; diiodomethane; copper (I) tert-butoxide; sodium hydrogencarbonate; copper(l) chloride; isopentyl nitrite; aluminium trichloride; In 1,4-dioxane; 1,2-dimethoxyethane; water;

Reference yield:

3,3'''-dimethyl-2',2'',4'',6'-tetranitro-m-quaterphenyl (111220-57-6) → 4'',6'-di-isopropoxy-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl (111221-04-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 82 percent / aluminium chloride

2: 0.43 mg / sodium sulphide nonahydrate/sodium hydrogen carbonate / H₂O; dioxane / 80 - 100 °C

3: 0.48 g / 3-methyl-butyl nitrite/di-iodomethane / 1.) room temp., 20 h; 2.) 75 deg C, 1 h

4: 220 mg / copper(I) chloride / 1,2-dimethoxy-ethane / 24 h / 70 °C

With sodium sulfide; diiodomethane; sodium hydrogencarbonate; copper(l) chloride; isopentyl nitrite; aluminium trichloride; In 1,4-dioxane; 1,2-dimethoxyethane; water;

upstream raw materials:

potassium isopropoxide

4'',6'-di-iodo-3,3'''-dimethyl-2',2''-dinitro-5,5'''-di-t-butyl-m-quaterphenyl

3-Iodotoluene

2,2',4,4'-tetranitro-1,1'-biphenyl