IrCl(η5-C5(CH3)5)((H3CCNNCHC6H3(OCH3)2)2)(PF6)

Base Information

• Chemical Name: IrCl(η5-C5(CH3)5)((H3CCNNCHC6H3(OCH3)2)2)(PF6)
• CAS No.: 1370365-98-2
• Molecular Formula: C₃₂H₄₁ClIrN₄O₄*F₆P
• Molecular Weight: 918.339
• Mol file: 1370365-98-2.mol

Synonyms:

Chemical Property of IrCl(η5-C5(CH3)5)((H3CCNNCHC6H3(OCH3)2)2)(PF6)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrCl(η5-C5(CH3)5)((H3CCNNCHC6H3(OCH3)2)2)(PF6)

There total 1 articles about IrCl(η5-C5(CH3)5)((H3CCNNCHC6H3(OCH3)2)2)(PF6) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

3,5-dimethoxybenzaldehdye (7311-34-4) + (η5-pentamethylcyclopentadienylato)IrCl(butane-2,3-diylidenebis(hydrazone)(PF6) (1370365-94-8) + tert-butylammonium hexafluorophosphate(V) (3109-63-5) → IrCl(η5-C5(CH3)5)((H3CCNNCHC6H3(OCH3)2)2)(PF6) (1370365-98-2)

Guidance literature:

With catalyst: H₂SO₄; In acetonitrile; Ar, standard Schlenk technique; reaction of Ir-complex with aldehyde in presence of catalytic amount of H2SO4, mixt. heated to reflux for 10 h, second portion of H2SO4 added, heated to reflux for 10 h; solvent removed (vac.), residue washed (ethanol, hexane), dried (vac.); elem. anal.;

DOI:10.1002/ejic.201100925

upstream raw materials:

3,5-dimethoxybenzaldehdye

(η5-pentamethylcyclopentadienylato)IrCl(butane-2,3-diylidenebis(hydrazone)(PF6)

tert-butylammonium hexafluorophosphate(V)