[ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf

Base Information

Chemical Name:[ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf
CAS No.:862672-98-8
Molecular Formula:CF₃O₃S*C₃₈H₆₈NP₃Re
Molecular Weight:967.163
Hs Code.:

[ReH<sub>4</sub>(PhP(CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>PCy<sub>2</sub>)2)(MeCN)]OTf

Synonyms:

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Chemical Property of [ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf

Chemical Property:

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Technology Process of [ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf

There total 2 articles about [ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 638197-87-2
[ReH4(η2-H2)(PhP(CH2CH2CH2P(C6H11)2)2)]CF3SO3

: 75-05-8,26809-02-9
acetonitrile

: 862672-98-8
[ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf

Guidance literature:: In benzene; byproducts: H2; under atm. of dry Ar; to Re complex in benzene added MeCN; mixt. heated at 60°C for 6 h; soln. concd.; Et2O added; solid filtered off; washed (Et2O); dried overnight (vac.); identified by NMR;
DOI:10.1016/j.jorganchem.2004.10.027

Reference yield:

: 638197-87-2
[ReH4(η2-H2)(PhP(CH2CH2CH2P(C6H11)2)2)]CF3SO3

: 67-64-1
acetone

: 75-05-8,26809-02-9
acetonitrile

: 192313-26-1
[Re(O)H₂(PhP(CH₂CH₂CH₂PCy₂)2)]OTf

: 862672-98-8
[ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf

Guidance literature:: In neat (no solvent); byproducts: H2; under atm. of dry Ar; soln. of Re complex (1 equiv.) and MeCN (0.2 equiv) in acetone (large excess) was heated at 60°C for 15 h; not isolated; monitored by NMR spectroscopy;
DOI:10.1016/j.jorganchem.2004.10.027

Reference yield:

: 862672-98-8
[ReH₄(PhP(CH₂CH₂CH₂PCy₂)2)(MeCN)]OTf

: 67-64-1
acetone

: 192313-26-1
[Re(O)H₂(PhP(CH₂CH₂CH₂PCy₂)2)]OTf

Guidance literature:: In acetone; byproducts: 2-propanol, CH3CN; under atm. of dry Ar; soln. of Re complex with neat acetone was heated at reflux temp. for 15 h; not isolated; monitored by NMR spectroscopy;
DOI:10.1016/j.jorganchem.2004.10.027