Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide

Base Information

• Chemical Name: Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide
• CAS No.: 100046-00-2
• Molecular Formula: C₁₈H₂₂N₂O₂
• Molecular Weight: 298.385
• Mol file: 100046-00-2.mol

Synonyms:

Chemical Property of Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide

There total 5 articles about Diazene, bis(2,4,6-trimethylphenyl)-, 1,2-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

[Zn(2-methyl-1-[methyl-(2-pyridin-2-yl-ethyl)amino]propane-2-thiolate)Mes] (1410236-31-5) + nitrosonium tetrafluoroborate → C-nitrosomesitylene dimer (100046-00-2,129615-67-4,129615-69-6)

Guidance literature:

In acetonitrile; for 2h;

DOI:10.1021/om300922m

Reference yield:

ethyl nitrite (109-95-5) → C-nitrosomesitylene dimer (100046-00-2,129615-67-4,129615-69-6)

Guidance literature:

With hydrogenchloride; chloroform; acetic acid;

DOI:10.1021/ja01315a043

Reference yield:

2,4,6-trimethylaniline (88-05-1) → 2,2',4,4',6,6'-hexamethylazobenzene-N,N-dioxide (100046-00-2,129615-67-4,129615-69-6)

Guidance literature:

With disodium hydrogenphosphate; potassium nitrososulfonate; water; acetone;

upstream raw materials:

ethyl nitrite

dichloromethane

[Zn(2-methyl-1-[methyl-(2-pyridin-2-yl-ethyl)amino]propane-2-thiolate)Mes]

2,4,6-trimethylaniline

Downstream raw materials:

N,N'-Bis-mesityl-glyoxaldiimin-N,N'-dioxid

2-nitrosomesitylene

N-(2,4,6-Trimethylphenyl)-formaldehydnitron

Refernces

• 1、 Orrell, Keith G.,Stephenson, David,Verlaque, James H.. "Monomer-Dimer Solution Equilibria of 2,4,6-Trialkylnitrosobenzenes and 2,4,6-Trialkylnitrosobenzene/Nitrosobenzene Mixtures. A Study Using One- and Twodimensional NMR Techniques". . p. 1297 - 1303. Retrieved 2007/10/02.