C₂₉H₅₀O₅Si

Base Information

Chemical Name:C₂₉H₅₀O₅Si
CAS No.:1459205-33-4
Molecular Formula:C₂₉H₅₀O₅Si
Molecular Weight:506.798
Hs Code.:

C<sub>29</sub>H<sub>50</sub>O<sub>5</sub>Si

Synonyms:

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Chemical Property of C₂₉H₅₀O₅Si

Chemical Property:

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Technology Process of C₂₉H₅₀O₅Si

There total 12 articles about C₂₉H₅₀O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1459205-32-3
(2S,3R,6S,7R,8S,9S,Z)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-3-(methoxymethoxy)-2,4,6,8-tetramethyldec-4-en-1-ol

: 1459205-33-4
C₂₉H₅₀O₅Si

Guidance literature:: With dimethyl sulfoxide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; at 20 ℃; for 0.75h; Inert atmosphere;
DOI:10.1039/c3ra42127a

Reference yield:

: 1459205-22-1
(2S,3S,4R,5S)-6-(tert-butyldiphenylsilyloxy)-3,5-dimethylhexane-2,4-diol

: 1459205-33-4
C₂₉H₅₀O₅Si

Guidance literature:: Multi-step reaction with 11 steps

1.1: sodium hydride / tetrahydrofuran; mineral oil / 0.33 h / 0 °C / Inert atmosphere

1.2: 6 h / 0 °C / Inert atmosphere

2.1: 2,6-dimethylpyridine / dichloromethane / 0.08 h / -78 °C / Inert atmosphere

2.2: 1 h / -78 - -20 °C / Inert atmosphere

3.1: ammonium fluoride; methanol / 48 h / 20 °C

4.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; dimethyl sulfoxide / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

5.1: potassium carbonate; 18-crown-6 ether / toluene / 3 h / 0 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / dichloromethane / 1.5 h / -78 - 0 °C / Inert atmosphere

7.1: manganese(IV) oxide / dichloromethane / 28 h / 20 °C / Inert atmosphere

8.1: titanium tetrachloride / dichloromethane / 0.25 h / 0 °C

8.2: 0.5 h / 0 °C

8.3: 2 h / -78 °C

9.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0.25 h / 0 °C

9.2: 12 h / 0 - 20 °C / Inert atmosphere

10.1: lithium borohydride / diethyl ether; methanol / 2 h / 0 - 20 °C

11.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; dimethyl sulfoxide / tetrahydrofuran / 0.75 h / 20 °C / Inert atmosphere

With 2,6-dimethylpyridine; methanol; manganese(IV) oxide; ammonium fluoride; lithium borohydride; 18-crown-6 ether; titanium tetrachloride; sodium hydride; diisobutylaluminium hydride; potassium carbonate; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene; mineral oil; 5.1: |Horner-Wadsworth-Emmons Olefination / 8.3: |Aldol Addition;
DOI:10.1039/c3ra42127a

Reference yield:

: 1459205-23-2
(2S,3R,4R,5S)-5-benzyloxy-1-(tert-butyldiphenylsilyloxy)-2,4-dimethylhexan-3-ol

: 1459205-33-4
C₂₉H₅₀O₅Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: 2,6-dimethylpyridine / dichloromethane / 0.08 h / -78 °C / Inert atmosphere

1.2: 1 h / -78 - -20 °C / Inert atmosphere

2.1: ammonium fluoride; methanol / 48 h / 20 °C

3.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; dimethyl sulfoxide / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

4.1: potassium carbonate; 18-crown-6 ether / toluene / 3 h / 0 °C / Inert atmosphere

5.1: diisobutylaluminium hydride / dichloromethane / 1.5 h / -78 - 0 °C / Inert atmosphere

6.1: manganese(IV) oxide / dichloromethane / 28 h / 20 °C / Inert atmosphere

7.1: titanium tetrachloride / dichloromethane / 0.25 h / 0 °C

7.2: 0.5 h / 0 °C

7.3: 2 h / -78 °C

8.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0.25 h / 0 °C

8.2: 12 h / 0 - 20 °C / Inert atmosphere

9.1: lithium borohydride / diethyl ether; methanol / 2 h / 0 - 20 °C

10.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; dimethyl sulfoxide / tetrahydrofuran / 0.75 h / 20 °C / Inert atmosphere

With 2,6-dimethylpyridine; methanol; manganese(IV) oxide; ammonium fluoride; lithium borohydride; 18-crown-6 ether; titanium tetrachloride; diisobutylaluminium hydride; potassium carbonate; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene; 4.1: |Horner-Wadsworth-Emmons Olefination / 7.3: |Aldol Addition;
DOI:10.1039/c3ra42127a