diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate

Base Information

• Chemical Name: diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate
• CAS No.: 176693-97-3
• Molecular Formula: C₃₄H₃₂N₂O₆
• Molecular Weight: 564.638
• Mol file: 176693-97-3.mol

Synonyms:

Chemical Property of diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate

Chemical Property:

Purity/Quality:

ETHYL-1-(2-(3-(ETHOXYCARBONYL)-5-HYDROXY-2-METHYL-1H-BENZO(G)INDOL-1-YL)ETHYL)-5-HYDROXY-2-METHYL-1H-BENZO(G)INDOLE-3-CARBOXYLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate

There total 2 articles about diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

diethyl 3,3'-(ethane-1,2-diyldiimino)dibutenoate (10054-25-8) + [1,4]naphthoquinone (130-15-4) → diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate (176693-97-3)

Guidance literature:

With acetic acid; at 50 - 60 ℃; for 5h;

Reference yield:

ethyl acetoacetate (141-97-9) → diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate (176693-97-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / 0.5 h / Ambient temperature

2: 59 percent / glacial AcOH / 5 h / 50 - 60 °C

With acetic acid;

Reference yield: 93.0%

diethyl 5,5'-dihydroxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate (176693-97-3) + methyl iodide (74-88-4) → diethyl 5,5'-dimethoxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate (176693-98-4)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; acetone; for 50h; Heating;

upstream raw materials:

diethyl 3,3'-(ethane-1,2-diyldiimino)dibutenoate

[1,4]naphthoquinone

ethyl acetoacetate

Downstream raw materials:

diethyl 5,5'-dimethoxy-2,2'-dimethyl-1,1'-(ethane-1,2-diyl)di(1H-benzo[g]indole)-3,3'-dicarboxylate

Refernces