(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

Base Information

Chemical Name:(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane
CAS No.:1313511-86-2
Molecular Formula:C₃₅H₆₄O₆Si₂
Molecular Weight:637.061
Hs Code.:

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

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Chemical Property of (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

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Technology Process of (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

There total 13 articles about (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₉H₅₀O₆Si

: 69739-34-0
t-butyldimethylsiyl triflate

: 1313511-86-2
(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1039/c0ob01253j

Reference yield:

: C₁₇H₂₃NO₄

: 1313511-86-2
(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: Multi-step reaction with 11 steps

1.1: sodium tetrahydroborate / ethanol; water; dimethyl sulfoxide / 0.5 h / 20 °C

2.1: acetic acid; zinc / ethanol / 2 h / 20 °C

3.1: 1H-imidazole / N,N-dimethyl-formamide / 6 h / 20 °C

4.1: camphor-10-sulfonic acid / dichloromethane / 20 °C

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

6.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / 0 °C

7.1: sodium dihydrogenphosphate; sodium chlorite / 2-methyl-but-2-ene; water; tert-butyl alcohol / 0.5 h / 0 °C

8.1: 1,1'-carbonyldiimidazole / dichloromethane / 0 °C

9.1: tert.-butyl lithium / diethyl ether; pentane / 0.25 h / -78 °C

9.2: -78 °C

10.1: L-Selectride / tetrahydrofuran / 1 h / -78 °C

11.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C

With 1H-imidazole; 2,6-dimethylpyridine; sodium chlorite; sodium tetrahydroborate; sodium dihydrogenphosphate; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; tert.-butyl lithium; sulfur trioxide pyridine complex; L-Selectride; acetic acid; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; 1,1'-carbonyldiimidazole; zinc; In tetrahydrofuran; 2-methyl-but-2-ene; diethyl ether; ethanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; tert-butyl alcohol; pentane; 6.1: Parikh-Doering oxidation;
DOI:10.1039/c0ob01253j

Reference yield:

: C₁₇H₂₅NO₄

: 1313511-86-2
(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: Multi-step reaction with 10 steps

1.1: acetic acid; zinc / ethanol / 2 h / 20 °C

2.1: 1H-imidazole / N,N-dimethyl-formamide / 6 h / 20 °C

3.1: camphor-10-sulfonic acid / dichloromethane / 20 °C

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

5.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / 0 °C

6.1: sodium dihydrogenphosphate; sodium chlorite / 2-methyl-but-2-ene; water; tert-butyl alcohol / 0.5 h / 0 °C

7.1: 1,1'-carbonyldiimidazole / dichloromethane / 0 °C

8.1: tert.-butyl lithium / diethyl ether; pentane / 0.25 h / -78 °C

8.2: -78 °C

9.1: L-Selectride / tetrahydrofuran / 1 h / -78 °C

10.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C

With 1H-imidazole; 2,6-dimethylpyridine; sodium chlorite; sodium dihydrogenphosphate; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; tert.-butyl lithium; sulfur trioxide pyridine complex; L-Selectride; acetic acid; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; 1,1'-carbonyldiimidazole; zinc; In tetrahydrofuran; 2-methyl-but-2-ene; diethyl ether; ethanol; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol; pentane; 5.1: Parikh-Doering oxidation;
DOI:10.1039/c0ob01253j