acide phenyl-1 indanecarboxylique-2 cis

Base Information

• Chemical Name: acide phenyl-1 indanecarboxylique-2 cis
• CAS No.: 101110-07-0
• Molecular Formula: C₁₆H₁₄O₂
• Molecular Weight: 238.286
• Mol file: 101110-07-0.mol

Synonyms:

Chemical Property of acide phenyl-1 indanecarboxylique-2 cis

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of acide phenyl-1 indanecarboxylique-2 cis

There total 13 articles about acide phenyl-1 indanecarboxylique-2 cis which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

3-phenyl-1H-indene (1961-97-3) + carbon dioxide (124-38-9,18923-20-1) → acide phenyl-1 indanecarboxylique-2 cis (101110-07-0,121926-17-8,121926-22-5)

Guidance literature:

3-phenyl-1H-indene; carbon dioxide; With triethylsilane; Triphenylsilyl chloride; ethylaluminum dichloride; In hexane; toluene; at 80 ℃; for 24h; under 22502.3 Torr; Autoclave;

With hydrogenchloride; In hexane; toluene; regioselective reaction; Autoclave;

DOI:10.1016/j.tetlet.2015.04.090

Reference yield:

C18H18O2 → trans acide phenyl-1 indanecarboxylique-2 trans (101110-07-0,121926-17-8,121926-22-5) + acide phenyl-1 indanecarboxylique-2 cis (101110-07-0,121926-17-8,121926-22-5)

Guidance literature:

C₁₈H₁₈O₂; With methanol; sodium hydroxide; water; In tetrahydrofuran; at 70 ℃; for 4h;

With hydrogenchloride; water;

Reference yield:

C18H18O2 → trans acide phenyl-1 indanecarboxylique-2 trans (101110-07-0,121926-17-8,121926-22-5) + acide phenyl-1 indanecarboxylique-2 cis (101110-07-0,121926-17-8,121926-22-5)

Guidance literature:

C₁₈H₁₈O₂; With methanol; sodium hydroxide; water; In tetrahydrofuran; at 70 ℃; for 4h;

With hydrogenchloride; water;

upstream raw materials:

3-phenyl-1H-indene-2-carboxylic acid

3-phenyl-1H-indene-2-carboxylic acid ethyl ester

ethyl (2Z)-2-(1-hydroxy-1-phenylmethyl)-3-phenylacrylate

benzaldehyde