ferrocenyl-pentacarbonylmanganese

Base Information

Chemical Name:ferrocenyl-pentacarbonylmanganese
CAS No.:116693-42-6
Molecular Formula:C₁₅H₉FeMnO₅
Molecular Weight:380.018
Hs Code.:

Synonyms:

Suppliers and Price of ferrocenyl-pentacarbonylmanganese

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ferrocenyl-pentacarbonylmanganese

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ferrocenyl-pentacarbonylmanganese

There total 1 articles about ferrocenyl-pentacarbonylmanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1271-15-4
lithiumferrocene

: 14516-54-2
bromopentacarbonylmanganese(I)

: 102-54-5,55404-68-7
ferrocene

: 116693-42-6,54841-23-5
ferrocenyl-pentacarbonylmanganese

: diferrocenylethane-1,2-dione

: cis-2-tetracarbonylmangana-1,3-diferrocenyl-1,3-propanedione

Guidance literature:: In tetrahydrofuran; under N2, soln. of freshly prepd. CpFeC5H4Li in THF added at -78°C to soln. of Mn(CO)Br in THF, warmed to room temp., stirred for 1.5 h; evapd. in vac., extd. with toluene, evapd., sepd. by column chromy. (Kieselgel (Matrex TM 60, 70-200 μ); pentane, CH2Cl2, CH2Cl2/Et2O (1/1)), recrystd. at -78°C from pentane (Mn(CO)5(CpFeC5H4)) or CH2Cl2/pentane (others); elem. anal.;
DOI:10.1016/0022-328X(87)80097-9

Reference yield: 73.0%

: 116693-42-6,54841-23-5
ferrocenyl-pentacarbonylmanganese

: 102-54-5,55404-68-7
ferrocene

: 116693-43-7,63517-24-8,63734-93-0
cis-tetracarbonyl(ferrocenyl)(triphenylphosphine)manganese

Guidance literature:: With triphenylphosphine; In toluene; under N2, Mn(CO)5(CpFeC5H4) and PPh3 dissolved in toluene, kept at 100°C for 4 h; evapd., extd. with pentane, concd., sepd. by column chromy. (Kieselgel;pentane, CH2Cl2), crystd. from pentane at -78°C;
DOI:10.1016/0022-328X(87)80097-9

Reference yield: 69.0%

: 116693-42-6,54841-23-5
ferrocenyl-pentacarbonylmanganese

: 12093-10-6
ferrocenecarboxaldehyde

: methyl ferrocenecarboxylate

Guidance literature:: With methanol; In methanol; under N2, soln. of Mn(CO)5(CpFeC5H4) in MeOH stirred at room temp. for 67 h; evapd., extd. with pentane, evapd., taken up in CH2Cl2, sepd. by columnchromy. (Kieselgel, CH2Cl2);
DOI:10.1016/0022-328X(87)80097-9