η5-cyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)

Base Information

Chemical Name:η5-cyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)
CAS No.:116693-43-7
Molecular Formula:C₃₂H₂₄FeMnO₄P
Molecular Weight:614.299
Hs Code.:

Synonyms:

Suppliers and Price of η5-cyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of η5-cyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)

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Technology Process of η5-cyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)

There total 1 articles about η5-cyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 116693-42-6,54841-23-5
ferrocenyl-pentacarbonylmanganese

: 102-54-5,55404-68-7
ferrocene

: 116693-43-7,63517-24-8,63734-93-0
cis-tetracarbonyl(ferrocenyl)(triphenylphosphine)manganese

Guidance literature:: With triphenylphosphine; In toluene; under N2, Mn(CO)5(CpFeC5H4) and PPh3 dissolved in toluene, kept at 100°C for 4 h; evapd., extd. with pentane, concd., sepd. by column chromy. (Kieselgel;pentane, CH2Cl2), crystd. from pentane at -78°C;
DOI:10.1016/0022-328X(87)80097-9

Reference yield: 30.0%

: 63517-24-8,116693-43-7,63734-93-0
η5-cyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)

: 7789-20-0
water-d2

: 928164-40-3
η5-monodeuterocyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; under Ar; soln. of n-BuLi in hexane added to soln. of Fe-Mn complex in THF at -78°C; stirred (-78°C, 1.5 h); D2O added; stirred (-78°C, 30 min); warmed to 20°C; solvent removed; chromd. (Al2O3, benzene-hexane 1:1);
DOI:10.1007/s11172-006-0334-8