methyl epi-phenylcamphorate

Base Information

• Chemical Name: methyl epi-phenylcamphorate
• CAS No.: 127308-33-2
• Molecular Formula: C₁₆H₂₂O₂
• Molecular Weight: 246.349
• Mol file: 127308-33-2.mol

Synonyms:

Chemical Property of methyl epi-phenylcamphorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl epi-phenylcamphorate

There total 3 articles about methyl epi-phenylcamphorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl phenylcamphorate (127308-32-1) → methyl epi-phenylcamphorate (127308-33-2)

Guidance literature:

With sodium methylate; In methanol; for 120h; Heating;

DOI:10.1021/jo00300a021

Reference yield:

cis-(+)-Phenylcamphoric acid (87099-28-3) → methyl epi-phenylcamphorate (127308-33-2)

Guidance literature:

Multi-step reaction with 2 steps

2: sodium methoxide / methanol / Heating

With sodium methylate; In methanol;

DOI:10.1016/S0040-4039(00)81949-8

Reference yield:

benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → methyl epi-phenylcamphorate (127308-33-2)

Guidance literature:

Multi-step reaction with 3 steps

1: aluminium chloride

3: sodium methoxide / methanol / Heating

With aluminium trichloride; sodium methylate; In methanol;

DOI:10.1016/S0040-4039(00)81949-8

upstream raw materials:

methyl phenylcamphorate

cis-(+)-Phenylcamphoric acid

benzene

Downstream raw materials:

(1S,3R,4R)-methyl 3-<<(o-nitrophenyl)seleno>methyl>-4,5,5-trimethylcyclopentanecarboxylate

(-)-(1R,3R)-ethyl 2,3,3-trimethyl-4-methylidenecyclopentanemethanol