2,6-Dideoxy-3-O-methyl-arabino-hexopyranose

Base Information

• Chemical Name: 2,6-Dideoxy-3-O-methyl-arabino-hexopyranose
• CAS No.: 492-34-2
• Molecular Formula: C₇H₁₄O₄
• Molecular Weight: 162.186
• DSSTox Substance ID: DTXSID401263740
• Nikkaji Number: J239.741B

Synonyms:DTXSID401263740;2,6-Dideoxy-3-O-methyl-arabino-hexopyranose;492-34-2

Chemical Property of 2,6-Dideoxy-3-O-methyl-arabino-hexopyranose

Chemical Property:

• XLogP3: -0.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 162.08920892
• Heavy Atom Count: 11
• Complexity: 128

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1C(C(CC(O1)O)OC)O
• Isomeric SMILES: C[C@@H]1[C@H]([C@@H](CC(O1)O)OC)O

Technology Process of 2,6-Dideoxy-3-O-methyl-arabino-hexopyranose

There total 76 articles about 2,6-Dideoxy-3-O-methyl-arabino-hexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

14β,20-dihydroxy-18-oic (18->20) lactone-5-pregnene 3-O-β-D-glucopyranosyl-(1->6)-β-D-glucopyranosyl-(1->4)-α-L-cymaropyranosyl-(1->4)-β-D-cymaropyranosyl-(1->4)-β-D-cymaropyranoside → β-D-glucose (492-61-5) + D-cymarose (492-34-2,492-35-3,492-36-4,530-01-8,45876-76-4,87037-59-0,87037-60-3,89253-98-5,89253-99-6,99436-74-5,99437-07-7,135502-90-8) + 2,6-dideoxy-3-O-methyl-α-L-ribo-hexose (492-34-2,492-35-3,492-36-4,530-01-8,87037-59-0,87037-60-3,89253-98-5,89253-99-6,99436-74-5,99437-07-7,135502-90-8,45876-76-4)

Guidance literature:

With hydrogenchloride; In methanol; for 2h; Reflux;

DOI:10.1016/j.fitote.2011.01.022

Reference yield:

14β,20-dihydroxy-18-oic (18->20) lactone-5-pregnene 3-O-β-D-glucopyranosyl-(1->6)-β-D-glucopyranosyl-(1->4)-α-L-cymaropyranosyl-(1->4)-β-D-cymaropyranosyl-(1->4)-β-D-cymaropyranoside → β-D-glucose (492-61-5) + D-cymarose (492-34-2,492-35-3,492-36-4,530-01-8,45876-76-4,87037-59-0,87037-60-3,89253-98-5,89253-99-6,99436-74-5,99437-07-7,135502-90-8) + 2,6-dideoxy-3-O-methyl-α-L-ribo-hexose (492-34-2,492-35-3,492-36-4,530-01-8,87037-59-0,87037-60-3,89253-98-5,89253-99-6,99436-74-5,99437-07-7,135502-90-8,45876-76-4)

Guidance literature:

With hydrogenchloride; In methanol; for 2h; Reflux;

DOI:10.1016/j.fitote.2011.01.022

Reference yield:

gymsyloside E → D-cymarose (492-34-2,492-35-3,530-01-8,45876-76-4,87037-59-0,87037-60-3,89253-98-5,89253-99-6,99436-74-5,99437-07-7,135502-90-8,492-36-4) + D-Glucose (2280-44-6) + D-oleandropyranose (909877-35-6) + methyl 6-deoxy-3-O-D-glucopyranose (484-36-6,484-37-7,523-75-1,25672-81-5,78185-80-5,78185-81-6,118333-77-0)

Guidance literature:

With hydrogenchloride; In 1,4-dioxane; water; at 80 ℃; for 3h;

DOI:10.3390/molecules25112525

upstream raw materials:

Bouceroside-ADC

Bouceroside-ANC

Bouceroside-BDO

Bouceroside-BNO

Downstream raw materials:

methyl β-D-cymaropyranoside

methyl 2,6-dideoxy-3-O-methyl-α-D-ribo-hexopyranoside

D-cymaronic acid acid phenylhydrazide

C₂₁H₂₂O₆

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