tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane

Base Information

Chemical Name:tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane
CAS No.:131156-46-2
Molecular Formula:C₂₈H₄₀O₄Si
Molecular Weight:468.709
Hs Code.:

Synonyms:

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Chemical Property of tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane

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Technology Process of tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane

There total 13 articles about tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 946133-73-9
(3aR,5R,6S,6aR)-5-((R)-3-Hydroxy-1-methyl-propyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

: 131156-46-2
tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole / dimethylformamide

2: PDC, Ac₂O / CH₂Cl₂

4: H₂ / Pd/C

With 1H-imidazole; dipyridinium dichromate; hydrogen; acetic anhydride; palladium on activated charcoal; In dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 127223-28-3
(3aR,5R,6S,6aR)-5-ethynyl-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol

: 131156-46-2
tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane

Guidance literature:: Multi-step reaction with 11 steps

1: 95 percent / NBS / CH₂Cl₂

2: 80 percent / Bu₃SnH, AIBN / toluene

3: 92 percent / 50percent aq. AcOH / 50 °C

4: 88 percent / PCC, NaOAc / CH₂Cl₂

5: 100 percent / DBU / CH₂Cl₂

6: 95 percent / H₂ / Rh-Al₂O₃ / ethyl acetate / 2585.7 Torr

7: LiAlH₄ / diethyl ether

8: imidazole / dimethylformamide

9: PDC, Ac₂O / CH₂Cl₂

11: H₂ / Pd/C

With 1H-imidazole; N-Bromosuccinimide; lithium aluminium tetrahydride; dipyridinium dichromate; 2,2'-azobis(isobutyronitrile); hydrogen; tri-n-butyl-tin hydride; sodium acetate; acetic anhydride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; pyridinium chlorochromate; palladium on activated charcoal; rhodium on alumina; In diethyl ether; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene;

Reference yield:

: (3aR,3bS,7aR,8aR)-2,2-Dimethyl-7-methylene-hexahydro-[1,3]dioxolo[4,5]furo[3,2-b]pyran-5-one

: 131156-46-2
tert-Butyl-diphenyl-[(R)-3-((3aR,5R,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butoxy]-silane

Guidance literature:: Multi-step reaction with 7 steps

1: 100 percent / DBU / CH₂Cl₂

2: 95 percent / H₂ / Rh-Al₂O₃ / ethyl acetate / 2585.7 Torr

3: LiAlH₄ / diethyl ether

4: imidazole / dimethylformamide

5: PDC, Ac₂O / CH₂Cl₂

7: H₂ / Pd/C

With 1H-imidazole; lithium aluminium tetrahydride; dipyridinium dichromate; hydrogen; acetic anhydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium on activated charcoal; rhodium on alumina; In diethyl ether; dichloromethane; ethyl acetate; N,N-dimethyl-formamide;