(o-toluidine)chromium tricarbonyl

Base Information

Chemical Name:(o-toluidine)chromium tricarbonyl
CAS No.:31833-43-9
Molecular Formula:C₁₀H₉CrNO₃
Molecular Weight:243.182
Hs Code.:

Synonyms:

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Chemical Property of (o-toluidine)chromium tricarbonyl

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Technology Process of (o-toluidine)chromium tricarbonyl

There total 1 articles about (o-toluidine)chromium tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 95-53-4
o-toluidine

: 31833-43-9,31833-44-0,12083-33-9
(o-toluidine)chromium tricarbonyl

Guidance literature:: In diethylene glycol;

Reference yield: 96.0%

: 3592-47-0
Benzaldehyde-d

: 31833-43-9,31833-44-0,12083-33-9
(o-toluidine)chromium tricarbonyl

: (CO)3CrC₆H₄(CH₃)(NC⁽²⁾HC₆H₅)

: 134572-47-7
tricarbonyl(η6-α-deuteriobenzylidene-o-toluidine)chromium

Guidance literature:: With catalyst: p-toluene-sulfonic acid; In toluene; byproducts: H2O; under N2; Cr complex and aldehyde dissolved in toluene, addn. of small amounts of catalyst, mixt. refluxed in Dean-Stark apparatus (azeotropic water removal) at 120-140°C until H2O ceased to be produced; cooled, filtered, evapn., residue contained the E and Z isomers (detected 1H NMR spect.), washed, recrystn. (light petroleum) gave pure E isomer, elem. anal.; Z isomer not isolated from mother liquors;
DOI:10.1039/DT9940000289

Reference yield: 87.0%

: 31833-43-9,31833-44-0,12083-33-9
(o-toluidine)chromium tricarbonyl

: 100-52-7
benzaldehyde

: N-benzylidene-2-methylaniline tricarbonylchromium

: (N-benzylidene-η6-o-methylaniline)tricarbonylchromium

Guidance literature:: With catalyst: p-toluene-sulfonic acid; In toluene; byproducts: H2O; under N2; Cr complex and aldehyde dissolved in toluene, addn. of small amounts of catalyst, mixt. refluxed in Dean-Stark apparatus (azeotropic water removal) at 120-140°C until H2O ceased to be produced; cooled, filtered, evapn., recrystn. (light petroleum); elem. anal. of the E isomer; the Z isomer detected 1H NMR spect. in the mother-liquor after recrystn., Z isomer not isolated; mole ratio E : Z isomer = 91 : 9;
DOI:10.1039/DT9940000289