Fe(C₅(CH₃)5)(C₄H₂N(SC₆H₅)2)

Base Information

Chemical Name:Fe(C₅(CH₃)5)(C₄H₂N(SC₆H₅)2)
CAS No.:1008761-63-4
Molecular Formula:C₂₆H₂₇FeNS₂
Molecular Weight:473.486
Hs Code.:

Fe(C<sub>5</sub>(CH<sub>3</sub>)5)(C<sub>4</sub>H<sub>2</sub>N(SC<sub>6</sub>H<sub>5</sub>)2)

Synonyms:

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Chemical Property of Fe(C₅(CH₃)5)(C₄H₂N(SC₆H₅)2)

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Technology Process of Fe(C₅(CH₃)5)(C₄H₂N(SC₆H₅)2)

There total 2 articles about Fe(C₅(CH₃)5)(C₄H₂N(SC₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

: 1008761-75-8
(+)-(R(p))-2'-phenylthio-1,2,3,4,5-pentamethylazaferrocene

: 1008761-75-8
(-)-(S(p))-2'-phenylthio-1,2,3,4,5-pentamethylazaferrocene

: 882-33-7
diphenyldisulfane

: 1008761-63-4
Fe(C₅(CH₃)5)(C₄H₂N(SC₆H₅)2)

Guidance literature:: With sec-butyllithium; (-)-sparteine; In diethyl ether; addn. of (-)-sparteine to a soln. of iron complex in Et2O, cooling to -78°C, addn. of sec-BuLi, stirring for 4 h, addn. of Ph2S2, warmingto room temp., stirring for 15 min; addn. of silica gel, concn. in vac., flash column chromy.;
DOI:10.1039/b715323f

Reference yield: 17.0%

: 183619-19-4
1',2',3',4',5'-pentamethylazaferrocene

: 882-33-7
diphenyldisulfane

: 1008761-75-8
(+)-(R(p))-2'-phenylthio-1,2,3,4,5-pentamethylazaferrocene

: 1008761-75-8
(-)-(S(p))-2'-phenylthio-1,2,3,4,5-pentamethylazaferrocene

: 1008761-63-4
Fe(C₅(CH₃)5)(C₄H₂N(SC₆H₅)2)

Guidance literature:: With sec-butyllithium; (-)-sparteine; In diethyl ether; hexane; addn. of 1.2 equivs. of (-)-sparteine to a soln. of iron complex in Et2O, cooling to -78°C, addn. of 1.2 equivs. of sec-BuLi in hexanes, stirring for 4 h, addn. of a soln. of Ph2S2 in Et2O, stirring at room temp. for 15 min, repeating addns.; addn. of SiO2, concn., flash column chromy. (10-20% EtOAc/5% Et3N/petroleum ether); not sepd., obtained as a mixt. of stereoisomers in 90% ee (S-isomer) in 60% yield; HPLC anal. (Chiralcel AD, 1% iPrOH/hexane);
DOI:10.1039/b715323f