(±)-pseudoheliotridane

Base Information

Chemical Name:(±)-pseudoheliotridane
CAS No.:15861-66-2
Molecular Formula:C₈H₁₅N
Molecular Weight:125.214
Hs Code.:

Synonyms:

Suppliers and Price of (±)-pseudoheliotridane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (±)-pseudoheliotridane

Chemical Property:

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Technology Process of (±)-pseudoheliotridane

There total 2 articles about (±)-pseudoheliotridane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80664-38-6
1-(3-butenyl)-5-(phenylthio)-2-pyrrolidinone

: 567-38-4,15861-66-2,17463-81-9,35418-35-0,35418-36-1,76548-10-2,517-24-8
(±)-pseudoheliotridane

: 13618-93-4
indolizidine

Guidance literature:: With lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) benzene, reflux, 7 h; 2.) ether, reflux 6 h;
DOI:10.1021/ja00338a033

Reference yield:

: 86953-79-9
tert-butyl pyrrolidine-1-carboxylate

: 567-38-4,15861-66-2,17463-81-9,35418-35-0,35418-36-1,76548-10-2,517-24-8
(±)-pseudoheliotridane

Guidance literature:: Multi-step reaction with 3 steps

1: sec-BuLi, TMEDA / 1) ether, -78 deg C, 2) 3 h

2: 1) TFA, 2) K₂CO₃ / 1) DCM, 5 deg C, 30 min, 2) CH₃CN, reflux, 2 h

3: 1,4-dicyanonaphthalene / propan-2-ol / 3 h / Irradiation; stereoselctivity, other amines

With N,N,N,N,-tetramethylethylenediamine; naphthalene-1,4-dicarbonitrile; sec.-butyllithium; potassium carbonate; trifluoroacetic acid; In isopropyl alcohol;
DOI:10.1016/S0040-4039(00)79035-6