hexane-1,6-diylbis(triphenylphosphonium)iodide

Base Information

• Chemical Name: hexane-1,6-diylbis(triphenylphosphonium)iodide
• CAS No.: 19100-92-6
• Molecular Formula: C₄₂H₄₂P₂*2I
• Molecular Weight: 862.552
• Mol file: 19100-92-6.mol

Synonyms:

Chemical Property of hexane-1,6-diylbis(triphenylphosphonium)iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexane-1,6-diylbis(triphenylphosphonium)iodide

There total 4 articles about hexane-1,6-diylbis(triphenylphosphonium)iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,6-diiodohexane (629-09-4) + triphenylphosphine (603-35-0) → hexane-1,6-diylbis(triphenylphosphonium)iodide (19100-92-6)

Guidance literature:

In acetonitrile; Inert atmosphere; Reflux;

DOI:10.1021/acs.jmedchem.9b00595

Reference yield:

6-chloro-1-hexanol (2009-83-8) → hexane-1,6-diylbis(triphenylphosphonium)iodide (19100-92-6)

Guidance literature:

Multi-step reaction with 2 steps

1: NaI / acetone / Heating

2: acetone / Heating

With sodium iodide; In acetone;

DOI:10.1039/j39680001331

Reference yield:

1 ,6-dibromohexane (629-03-8) → hexane-1,6-diylbis(triphenylphosphonium)iodide (19100-92-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium iodide / acetone / 20 °C / Inert atmosphere

2: acetonitrile / Inert atmosphere; Reflux

With sodium iodide; In acetone; acetonitrile; 1: |Finkelstein Reaction;

DOI:10.1021/acs.jmedchem.9b00595

upstream raw materials:

1-iodohexan-6-ol

triphenylphosphine

6-chloro-1-hexanol

1 ,6-dibromohexane

Downstream raw materials:

Tetra-P-phenyl-P,P'-hexanediyl-bis-phosphine oxide