(+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one

Base Information

• Chemical Name: (+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one
• CAS No.: 93175-91-8
• Molecular Formula: C₂₇H₃₀O₄
• Molecular Weight: 418.533
• Mol file: 93175-91-8.mol

Synonyms:

Chemical Property of (+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one

There total 3 articles about (+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cardamomin (19309-14-9) → (+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one (93175-91-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 47 percent / DMSO, pyridine / 26 h / 120 °C

2: 0.08 g / 3percent H₂SO₄ / ethanol / 10 h / Heating

3: 0.04 g / K₂CO₃ / acetone / 16 h / Heating

With pyridine; sulfuric acid; potassium carbonate; dimethyl sulfoxide; In ethanol; acetone;

DOI:10.1071/CH9841739

Reference yield:

(+/-)-(E)-1-<5',7'-dimethoxy-2'-methyl-2'-(4methylpent-3-enyl)-2'H-1-benzopyran-6'-yl>-3-phenylprop-2-en-1-one (93175-88-3) → (+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one (93175-91-8)

Guidance literature:

With sulfuric acid; In ethanol; for 10h; Heating;

DOI:10.1071/CH9841739

Reference yield:

(E/Z)-3,7-dimethyl-2,6-octadienal (5392-40-5,96680-15-8) → (+/-)-(E)-(5'-isopropylidene-7',9'-dimethoxy-2'-methyl-3',4',5',6'-tetrahydro-2',6'-methano-2'H-1-benzoxocin-8'-yl)-3-phenylprop-2-en-1-one (93175-91-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 47 percent / DMSO, pyridine / 26 h / 120 °C

2: 0.08 g / 3percent H₂SO₄ / ethanol / 10 h / Heating

3: 0.04 g / K₂CO₃ / acetone / 16 h / Heating

With pyridine; sulfuric acid; potassium carbonate; dimethyl sulfoxide; In ethanol; acetone;

DOI:10.1071/CH9841739

upstream raw materials:

(+/-)-(E)-1-<5',7'-dimethoxy-2'-methyl-2'-(4methylpent-3-enyl)-2'H-1-benzopyran-6'-yl>-3-phenylprop-2-en-1-one

cardamomin

(E/Z)-3,7-dimethyl-2,6-octadienal