PdCl(CH₃)((C₆H₅)2PC₆H₄NCH(C₆H₅))

Base Information

• Chemical Name: PdCl(CH₃)((C₆H₅)2PC₆H₄NCH(C₆H₅))
• CAS No.: 231608-15-4
• Molecular Formula: C₂₆H₂₃ClNPPd
• Molecular Weight: 522.322
• Mol file: 231608-15-4.mol

Synonyms:

Chemical Property of PdCl(CH₃)((C₆H₅)2PC₆H₄NCH(C₆H₅))

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of PdCl(CH₃)((C₆H₅)2PC₆H₄NCH(C₆H₅))

There total 1 articles about PdCl(CH₃)((C₆H₅)2PC₆H₄NCH(C₆H₅)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

chloromethyl(1,5-cyclooctadiene)palladium(II) + N-benzylidene-2-(diphenylphosphino)benzeneamine (154638-80-9) → PdCl(CH3)((C6H5)2PC6H4NCH(C6H5)) (231608-15-4,339086-26-9)

Guidance literature:

In dichloromethane; (inert atm.); soln. of Pd complex in CH2Cl2 treated with CH2Cl2 soln. ofligand precursor and stirred vigorously overnight; mixt. filtered; solvent removed; residue washed with hexane and dried under vac.; elem. anal.;

DOI:10.1016/S0022-328X(02)01203-2

Reference yield: 83.0%

PdCl(CH3)((C6H5)2PC6H4NCH(C6H5)) (231608-15-4,339086-26-9) + water (7732-18-5) + silver trifluoromethanesulfonate (2923-28-6) → [((C6H5)2PC6H4NCHC6H5)Pd(CH3)(H2O)](1+)*CF3SO3(1-)=[((C6H5)2PC6H4NCHC6H5)Pd(CH3)(H2O)](CF3SO3) (479370-03-1)

Guidance literature:

In dichloromethane; under N2, mixt. was stirred for 2 h at room temp.; mixt. was filtered, filtrate was concd., residue was washed with ether; elem. anal.;

DOI:10.1021/om020662s

upstream raw materials:

N-benzylidene-2-(diphenylphosphino)benzeneamine

Downstream raw materials:

[((C₆H₅)2PC₆H₄NCHC₆H₅)Pd(CH₃)(H₂O)]⁽¹⁺⁾*CF₃SO₃^(1-)=[((C₆H₅)2PC₆H₄NCHC₆H₅)Pd(CH₃)(H₂O)](CF₃SO₃)