N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate

Base Information

• Chemical Name: N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate
• CAS No.: 1404194-11-1
• Molecular Formula: C₁₇H₂₆N*FO₃S
• Molecular Weight: 343.463
• Mol file: 1404194-11-1.mol

Synonyms:

Chemical Property of N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate

There total 1 articles about N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

Methyl fluorosulfonate (421-20-5) + 2,4,6-tri(isopropyl)benzonitrile (101254-85-7) → N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate (1404194-11-1)

Guidance literature:

at 45 ℃; for 45h;

DOI:10.1021/jo301983s

Reference yield:

N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate (1404194-11-1) → C18H29NO (1404194-17-7)

Guidance literature:

Multi-step reaction with 2 steps

1: [D₃]acetonitrile / 0.08 h / -20 °C

2: methanol / dichloromethane / -78 °C

With methanol; In dichloromethane; [D₃]acetonitrile;

DOI:10.1021/jo301983s

Reference yield:

N-methyl-2,4,6-trisisopropylbenzonitrilium fluorosulfonate (1404194-11-1) → C18H30NO(1+)*FO3S(1-) (1404194-18-8)

Guidance literature:

Multi-step reaction with 3 steps

1: [D₃]acetonitrile / 0.08 h / -20 °C

2: methanol / dichloromethane / -78 °C

3: [D₃]acetonitrile / 0.08 h / -20 °C

With methanol; In dichloromethane; [D₃]acetonitrile;

DOI:10.1021/jo301983s

upstream raw materials:

Methyl fluorosulfonate

2,4,6-tri(isopropyl)benzonitrile

Downstream raw materials:

C₁₈H₂₉NO

C₁₈H₃₀NO⁽¹⁺⁾*FO₃S^(1-)

C₁₈H₃₀NO⁽¹⁺⁾*FO₃S^(1-)