[platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)]

Base Information

Chemical Name:[platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)]
CAS No.:1235613-77-0
Molecular Formula:C₃₈H₂₄F₆N₂Pt
Molecular Weight:817.692
Hs Code.:

[platinum(II)diphenyl(bis(4-CF<sub>3</sub>C<sub>6</sub>H<sub>4</sub>-imino)acenaphthene)]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)]

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Technology Process of [platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)]

There total 1 articles about [platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 226071-20-1
bis(4-trifluoromethylphenyl)acenaphthenequinonediimine

: cis-(PtPh₂(SMe₂)2)

: 1235613-77-0
[platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)]

Guidance literature:: In toluene; mixt. of Pt complex (0.78 mmol) and diimine (0.78 mmol) stirred overnight at room temp.; B. J. Wik et al., J. Am. Chem. Soc. 2006, 128, 2682-2696; chromd. on silica with CH2Cl2/pentane; elem. anal.;
DOI:10.1002/ejic.200900975

Reference yield: 56.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 1235613-77-0
[platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)]

: 75-05-8,26809-02-9
acetonitrile

: 1235614-04-6
[platinum(II)(phenyl)(acetonitrile)(bis(4-CF₃C₆H₄-imino)acenaphthene)]tetrafluoroborate

Guidance literature:: In acetonitrile; byproducts: C6H6; HBF4*Et2O (0.16 mmol) added dropwise to stirred soln. of Pt complex (0.12 mmol) at 0°C under Ar, soln. stirred and gradually warmed to ambient temp., kept for 1 h; solvent removed under vac., residue washed with ether, recrystd. from CH2Cl2 soln. layered with ether; elem. anal.;
DOI:10.1002/ejic.200900975

Reference yield:

: 2206-26-0
[D₃]acetonitrile

: 1493-13-6
trifluorormethanesulfonic acid

: 1235613-77-0
[platinum(II)diphenyl(bis(4-CF₃C₆H₄-imino)acenaphthene)]

: [platinum(II)(acetonitrile-d3)2(bis(4-CF₃C₆H₄-imino)acenaphthene)](triflate)2

Guidance literature:: In dichloromethane-d2; [D₃]acetonitrile; byproducts: C6H6; C(2)H2Cl2 layered on top of Pt comlex (0.01 mmol) soln. (C(2)H2Cl2), soln. of TfOH (0.035 mmol) (NCC(2)H3) added, tube shaken, kept overnight at50°C;
DOI:10.1002/ejic.200900975