(C₆H₅)3CH₂C₂HN₃⁽¹⁺⁾*Br^(1-)=(C₆H₅)3CH₂HC₂N₃Br

Base Information

• Chemical Name: (C₆H₅)3CH₂C₂HN₃⁽¹⁺⁾*Br^(1-)=(C₆H₅)3CH₂HC₂N₃Br
• CAS No.: 1352802-50-6
• Molecular Formula: Br*C₂₁H₁₈N₃
• Molecular Weight: 392.298
• Mol file: 1352802-50-6.mol

Synonyms:

Chemical Property of (C₆H₅)3CH₂C₂HN₃⁽¹⁺⁾*Br^(1-)=(C₆H₅)3CH₂HC₂N₃Br

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅)3CH₂C₂HN₃⁽¹⁺⁾*Br^(1-)=(C₆H₅)3CH₂HC₂N₃Br

There total 1 articles about (C₆H₅)3CH₂C₂HN₃⁽¹⁺⁾*Br^(1-)=(C₆H₅)3CH₂HC₂N₃Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

1,4-diphenyl-[1,2,3]-triazole (13148-78-2) + benzyl bromide (100-39-0) → (C6H5)3CH2C2HN3(1+)*Br(1-)=(C6H5)3CH2HC2N3Br (1352802-50-6)

Guidance literature:

at 100 ℃; for 72h; Neat (no solvent);

DOI:10.1021/om2010029

Reference yield: 44.0%

di-μ-bromo(dibromo)bis[1,3-di(propan-2-yl)-1,3-dihydro-2H-benzimidazol-2-ylidene]dipalladium(II) + (C6H5)3CH2C2HN3(1+)*Br(1-)=(C6H5)3CH2HC2N3Br (1352802-50-6) → trans-[PdBr2(1,3-diisopropylbenzimidazolin-2-ylidene)(C2N3CH2Ph3)]

Guidance literature:

With Ag₂O; In dichloromethane; byproducts: AgBr; exclusion of air and moisture; a mixt. of salt A*HBr (0.13 mmol), Pd-contg. compd. (0.06 mmol), and Ag2O (0.08 mmol) was stirred in CH2Cl2 at ambient temp. overnight shielded from light; the suspn. was filtered over Celite, the filtrate was removed in vac.; column chromy. (SiO2, ethyl acetate/hexane, 3:7); elem. anal.;

DOI:10.1021/om2010029

Reference yield:

di-μ-bromo(dibromo)bis[1,3-di(propan-2-yl)-1,3-dihydro-2H-benzimidazol-2-ylidene]dipalladium(II) + (C6H5)3CH2C2HN3(1+)*Br(1-)=(C6H5)3CH2HC2N3Br (1352802-50-6) → [Pd(trifluoroacetato)2(1,3-diisopropylbenzimidazolin-2-ylidene)(C2N3CH2Ph3)]

Guidance literature:

Multi-step reaction with 2 steps

1: Ag₂O / dichloromethane

2: acetonitrile

With Ag₂O; In dichloromethane; acetonitrile;

DOI:10.1021/om2010029

upstream raw materials:

1,4-diphenyl-[1,2,3]-triazole

benzyl bromide