Tl⁽¹⁺⁾*C₅H₄(CH₂)3NHC(O)OCH₂C₆H₅^(1-)=TlC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅

Base Information

• Chemical Name: Tl⁽¹⁺⁾*C₅H₄(CH₂)3NHC(O)OCH₂C₆H₅^(1-)=TlC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅
• CAS No.: 219125-92-5
• Molecular Formula: C₁₆H₁₈NO₂*Tl
• Molecular Weight: 460.707
• Mol file: 219125-92-5.mol

Synonyms:

Chemical Property of Tl⁽¹⁺⁾*C₅H₄(CH₂)3NHC(O)OCH₂C₆H₅^(1-)=TlC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tl⁽¹⁺⁾*C₅H₄(CH₂)3NHC(O)OCH₂C₆H₅^(1-)=TlC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅

There total 1 articles about Tl⁽¹⁺⁾*C₅H₄(CH₂)3NHC(O)OCH₂C₆H₅^(1-)=TlC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium cyclopentadienide + thallium (I) ethoxide (20398-06-5) + 3-bromopropylamine hydrochloride (5003-71-4) + benzyl chloroformate (501-53-1,94274-21-2) → Tl(1+)*C5H4(CH2)3NHC(O)OCH2C6H5(1-)=TlC5H4(CH2)3NHC(O)OCH2C6H5 (219125-92-5)

Guidance literature:

With 4-methyl-morpholine; In tetrahydrofuran; diethyl ether; reaction of amine hydrobromide with CpLi in THF (5°C, 20 h), reaction with CbzCl(Et2O, 25°C, 1.5 h, N-methylmorpholine), reaction with TlOEt (Et2O, 25°C, 0.5 d);

DOI:10.1021/ja982602c

Reference yield:

potassium hexafluorophosphate (17084-13-8) + dichloro(mesitylene)ruthenium(II) dimer + Tl(1+)*C5H4(CH2)3NHC(O)OCH2C6H5(1-)=TlC5H4(CH2)3NHC(O)OCH2C6H5 (219125-92-5) → (C6H3(CH3)3)RuC5H4(CH2)3NHC(O)OCH2C6H5(1+)*PF6(1-)=[(C6H3(CH3)3)RuC5H4(CH2)3NHC(O)OCH2C6H5]PF6 (219126-02-0)

Guidance literature:

In water; acetonitrile; reaction at 25°C;

DOI:10.1021/ja982602c

Reference yield:

potassium hexafluorophosphate (17084-13-8) + dichloro(benzene)ruthenium(II) dimer (37366-09-9) + Tl(1+)*C5H4(CH2)3NHC(O)OCH2C6H5(1-)=TlC5H4(CH2)3NHC(O)OCH2C6H5 (219125-92-5) → (C6H6)RuC5H4(CH2)3NHC(O)OCH2C6H5(1+)*PF6(1-)=[(C6H6)RuC5H4(CH2)3NHC(O)OCH2C6H5]PF6 (219125-97-0)

Guidance literature:

In water; acetonitrile; reaction at 25°C;

DOI:10.1021/ja982602c

upstream raw materials:

thallium (I) ethoxide

3-bromopropylamine hydrochloride

benzyl chloroformate

Downstream raw materials:

(C₆H₃(CH₃)3)RuC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=[(C₆H₃(CH₃)3)RuC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅]PF₆

(C₆H₆)RuC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=[(C₆H₆)RuC₅H₄(CH₂)3NHC(O)OCH₂C₆H₅]PF₆