[Mn(CO)3(4-NO₂C₆H₄NHNH₂)(PPh(OEt)2)2][BPh₄]

Base Information

Chemical Name:[Mn(CO)3(4-NO₂C₆H₄NHNH₂)(PPh(OEt)2)2][BPh₄]
CAS No.:186344-08-1
Molecular Formula:C₂₄H₂₀B*C₂₉H₃₇MnN₃O₉P₂
Molecular Weight:1007.75
Hs Code.:

[Mn(CO)3(4-NO<sub>2</sub>C<sub>6</sub>H<sub>4</sub>NHNH<sub>2</sub>)(PPh(OEt)2)2][BPh<sub>4</sub>]

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Chemical Property of [Mn(CO)3(4-NO₂C₆H₄NHNH₂)(PPh(OEt)2)2][BPh₄]

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Technology Process of [Mn(CO)3(4-NO₂C₆H₄NHNH₂)(PPh(OEt)2)2][BPh₄]

There total 1 articles about [Mn(CO)3(4-NO₂C₆H₄NHNH₂)(PPh(OEt)2)2][BPh₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 186344-30-9
tricarbonylhydridomanganese(I)(PPh(OEt)2)2

: 143-66-8
sodium tetraphenyl borate

: 100-16-3
4-nitrophenylhydrazone

: 186344-08-1
[Mn(CO)3(4-NO₂C₆H₄NHNH₂)(PPh(OEt)2)2][BPh₄]

Guidance literature:: With CF₃SO₃H; In dichloromethane; inert atmosphere; addn. of 1 equiv. TfOH to Mn-complex at -80°C, stirring at room temp. for 2 h, addn. of slight excess hydrazine at -80°C, stirring for 3 h, evapn., dissoln. in EtOH, addn. of excess NaBPh4 in EtOH (pptn.); collection (filtration), recrystn. (EtOH/CH2Cl2=1:4 v/v); elem. anal.;
DOI:10.1021/ic9608612

Reference yield:

: 186344-08-1
[Mn(CO)3(4-NO₂C₆H₄NHNH₂)(PPh(OEt)2)2][BPh₄]

: Mn(CO)3(O₂NC₆H₄NNH)(C₆H₅P(OC₂H₅)2)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Mn(CO)3(O₂NC₆H₄NNH)(C₆H₅P(OC₂H₅)2)2][B(C₆H₅)4]

Guidance literature:: With Pb(OAc)4; In dichloromethane; inert atmosphere; equimolar amts., stirring at -40°C for 20-30 min; filtration, solvent removal (vac.), EtOH addn., stirring (pptn.), collection (filtration), drying (vac.);
DOI:10.1021/ic9608612